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Thermochemistry of hydrated lithium borates
Li, J; Li, B; Gao, SY
1998-06-01
Source PublicationJOURNAL OF CHEMICAL THERMODYNAMICS
Volume30Issue:6Pages:681-688
SubtypeArticle
AbstractThe enthalpies of solution of the hydrated lithium berates Li2B4O7. 3H(2)O and LiB5O8. 5H(2)O in approximately 1 mol . dm(-3) aqueous hydrochloric acid, as well as the enthalpies of solution of H3BO3 in HCl(aq) and of LiCl . H2O in aqueous (hydrochloric acid + boric acid) were determined. With the incorporation of the standard molar enthalpies of formation Delta(f)H(m)(o) of LiCl . H2O(s), H3BO3(s), and H2O(l), the standard molar enthalpies of formation of these hydrated berates were obtained. An approach to correlate Delta(f)H(m)(o) of hydrated berates with Delta(f)H(m)(o) of corresponding cations in aqueous solution and Delta(f)H(m)(o)(H2O, l) was suggested from the point of view of structures, (C) 1998 Academic Press.
KeywordHydrated Lithium Borates Standard Molar Enthalpy Of Formation Solution Calorimetry Molar Enthalpy Of Solution
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordGIBBS ENERGIES ; AQUEOUS IONS ; MINERALS ; PREDICTION ; ENTHALPIES ; OXIDES
Indexed BySCI
Language英语
WOS Research AreaThermodynamics ; Chemistry
WOS SubjectThermodynamics ; Chemistry, Physical
WOS IDWOS:000074457900002
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6007
Collection青海盐湖研究所知识仓储
AffiliationChinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian, Peoples R China
Recommended Citation
GB/T 7714
Li, J,Li, B,Gao, SY. Thermochemistry of hydrated lithium borates[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,1998,30(6):681-688.
APA Li, J,Li, B,&Gao, SY.(1998).Thermochemistry of hydrated lithium borates.JOURNAL OF CHEMICAL THERMODYNAMICS,30(6),681-688.
MLA Li, J,et al."Thermochemistry of hydrated lithium borates".JOURNAL OF CHEMICAL THERMODYNAMICS 30.6(1998):681-688.
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