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Thermochemistry of hydrated lithium borates
Li, J; Li, B; Gao, SY
1998-06-01
发表期刊JOURNAL OF CHEMICAL THERMODYNAMICS
卷号30期号:6页码:681-688
文章类型Article
摘要The enthalpies of solution of the hydrated lithium berates Li2B4O7. 3H(2)O and LiB5O8. 5H(2)O in approximately 1 mol . dm(-3) aqueous hydrochloric acid, as well as the enthalpies of solution of H3BO3 in HCl(aq) and of LiCl . H2O in aqueous (hydrochloric acid + boric acid) were determined. With the incorporation of the standard molar enthalpies of formation Delta(f)H(m)(o) of LiCl . H2O(s), H3BO3(s), and H2O(l), the standard molar enthalpies of formation of these hydrated berates were obtained. An approach to correlate Delta(f)H(m)(o) of hydrated berates with Delta(f)H(m)(o) of corresponding cations in aqueous solution and Delta(f)H(m)(o)(H2O, l) was suggested from the point of view of structures, (C) 1998 Academic Press.
关键词Hydrated Lithium Borates Standard Molar Enthalpy Of Formation Solution Calorimetry Molar Enthalpy Of Solution
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]GIBBS ENERGIES ; AQUEOUS IONS ; MINERALS ; PREDICTION ; ENTHALPIES ; OXIDES
收录类别SCI
语种英语
WOS研究方向Thermodynamics ; Chemistry
WOS类目Thermodynamics ; Chemistry, Physical
WOS记录号WOS:000074457900002
引用统计
被引频次:29[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6007
专题青海盐湖研究所知识仓储
作者单位Chinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian, Peoples R China
推荐引用方式
GB/T 7714
Li, J,Li, B,Gao, SY. Thermochemistry of hydrated lithium borates[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,1998,30(6):681-688.
APA Li, J,Li, B,&Gao, SY.(1998).Thermochemistry of hydrated lithium borates.JOURNAL OF CHEMICAL THERMODYNAMICS,30(6),681-688.
MLA Li, J,et al."Thermochemistry of hydrated lithium borates".JOURNAL OF CHEMICAL THERMODYNAMICS 30.6(1998):681-688.
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