ISL OpenIR  > 青海盐湖研究所知识仓储
The thermodynamics of aqueous borate solutions 4. The standard association constant of ion pair [CaB(OH)(4)](+)
Sun, B; Yang, JZ; Song, PS; Deng, M; Gao, YY
1999
发表期刊ACTA CHIMICA SINICA
卷号57期号:9页码:992-996
文章类型Article
摘要Emfs for the cell without liquid junction:Pt, H-2(101.325kPa) \ Li2B4O7 (m(1)), CaCl2 (m(2)) \ AgCl - Ag are reported at five temperatures from 278.15 to 318.15 It. The standard association constant of ionic pair [CaB(OH)(4)](+), K-d is determined by fitting to the cell results. The dependence of pK(d) on temperature T is expressed by an empirical equation: pk(d) = 0.6857 - 359.72/ T - 4.632 x 10(-3) T. The other thermodynamic quantities of the association process are also calculated. The results show that the driving force for the ion association reaction is association entropy.
关键词Borate Ion Pair Association Constant Emf Pitzer Theory Association Entropy
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]CHLORIDE
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000082978300008
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6023
专题青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
推荐引用方式
GB/T 7714
Sun, B,Yang, JZ,Song, PS,et al. The thermodynamics of aqueous borate solutions 4. The standard association constant of ion pair [CaB(OH)(4)](+)[J]. ACTA CHIMICA SINICA,1999,57(9):992-996.
APA Sun, B,Yang, JZ,Song, PS,Deng, M,&Gao, YY.(1999).The thermodynamics of aqueous borate solutions 4. The standard association constant of ion pair [CaB(OH)(4)](+).ACTA CHIMICA SINICA,57(9),992-996.
MLA Sun, B,et al."The thermodynamics of aqueous borate solutions 4. The standard association constant of ion pair [CaB(OH)(4)](+)".ACTA CHIMICA SINICA 57.9(1999):992-996.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Sun, B]的文章
[Yang, JZ]的文章
[Song, PS]的文章
百度学术
百度学术中相似的文章
[Sun, B]的文章
[Yang, JZ]的文章
[Song, PS]的文章
必应学术
必应学术中相似的文章
[Sun, B]的文章
[Yang, JZ]的文章
[Song, PS]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。