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A new attempt to determine solution structure with theta-20 type powder diffractometer
Fang, CH; Fang, Y; Wang, LY; Song, DK
1999
发表期刊ACTA CHIMICA SINICA
卷号57期号:1页码:80-86
文章类型Article
摘要A new method for determining the structure of aqueous electrolyte solution using theta - 2 theta type powder diffractometer has been developed. The thermostatic super - thick liquid sample cells have been desired and the correction procedures for the diffraction intensity of window on the cell proposed. A very satisfactory experimental result of molten salt of hexaquamanganese nitrate has been obtained. A comparison between the radial distribution function curve with the theta - 2 theta type diffractometer and that with the theta - theta type diffractometer by the free surface scattering shows that the resolution has improved to some extent. The hydrogen bonding distance of 0.28nm from the cis-O-O interaction of 0.31nm in the first coordination shell in the octahedral complex ion of [Mn( H2O)(5)(ONO2)](+) and the Mn-N distance of 0.309nm in the contact ion pair have been clearly distinguished. Then the Mn-O(II) peak at 0.42nm from the trans-O-O peack at 0.44nm has been separated out. With the improvement of the resolution, some ripples occured in the high r zone. This is to be overcome.
关键词New Liquid Diffractometry Solution Structure Radial Distribution Function
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]X-RAY-DIFFRACTION
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000078453300014
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6027
专题青海盐湖研究所知识仓储
盐湖资源与化学实验室
作者单位1.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Peoples R China
2.Lanzhou Univ, Lanzhou 730000, Peoples R China
3.Minist Chem Ind, NW Inst Chem Engn, Litong 710600, Peoples R China
推荐引用方式
GB/T 7714
Fang, CH,Fang, Y,Wang, LY,et al. A new attempt to determine solution structure with theta-20 type powder diffractometer[J]. ACTA CHIMICA SINICA,1999,57(1):80-86.
APA Fang, CH,Fang, Y,Wang, LY,&Song, DK.(1999).A new attempt to determine solution structure with theta-20 type powder diffractometer.ACTA CHIMICA SINICA,57(1),80-86.
MLA Fang, CH,et al."A new attempt to determine solution structure with theta-20 type powder diffractometer".ACTA CHIMICA SINICA 57.1(1999):80-86.
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