ISL OpenIR  > 青海盐湖研究所知识仓储
Synthesis, characterization and magnetic study of mu-oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes
Li, YT; Yan, CW; Wang, HD
2000-12-01
发表期刊POLISH JOURNAL OF CHEMISTRY
卷号74期号:12页码:1655-1663
关键词Magnetism Copper(Ii) Lanthanide(Iii) Heterobinuclear Complexes Oxamido Bridging
摘要Tell new mu -oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes described by the overall formula Cu(Br(4)Obbz)Ln(phen)(2)NO3 (Ln = Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er), where Br(4)obbz denotes the oxamido-N,N'-bis(3,5-dibromobenzoato) and phen represents 1,10-phenanthroline, have been synthesized and characterized by the elemental analyses, magnetic moments (at room temperature), molar conductivity measurements and spectroscopic (IR, UV, ESR) studies. The temperature dependence of the magnetic susceptibility of Cu(Br(4)obbz)Gd(phen)(2)NO3 complex was measured over the range 4.2-300 K. The least-squares fit of the experimental susceptibilities based on the spin Hamiltonian operator, (H) over cap=-2J (S) over cap (1).(S) over cap (2), yielded J= +3.7 cm(-1). This result indicates the presence of a weak ferromagnetic spin-exchange interaction between Gd(III) and Cu(II) ions.
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6032
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Qufu Normal Univ, Dept Chem, Shandong 273165, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Li, YT,Yan, CW,Wang, HD. Synthesis, characterization and magnetic study of mu-oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes[J]. POLISH JOURNAL OF CHEMISTRY,2000,74(12):1655-1663.
APA Li, YT,Yan, CW,&Wang, HD.(2000).Synthesis, characterization and magnetic study of mu-oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes.POLISH JOURNAL OF CHEMISTRY,74(12),1655-1663.
MLA Li, YT,et al."Synthesis, characterization and magnetic study of mu-oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes".POLISH JOURNAL OF CHEMISTRY 74.12(2000):1655-1663.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Li, YT]的文章
[Yan, CW]的文章
[Wang, HD]的文章
百度学术
百度学术中相似的文章
[Li, YT]的文章
[Yan, CW]的文章
[Wang, HD]的文章
必应学术
必应学术中相似的文章
[Li, YT]的文章
[Yan, CW]的文章
[Wang, HD]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。