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Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K
Jiang, YC; Gao, SY; Xia, SP; Wang, JJ; Zhuo, KL; Hu, MC
2002-12-01
Source PublicationJOURNAL OF CHEMICAL THERMODYNAMICS
Volume34Issue:12Pages:1959-1973
SubtypeArticle
AbstractA non-liquid-junction electrochemical cell composed of a potassium ion selective electrode(K-ISE) against a chloride ion selective electrode (Cl-ISE) as a reference electrode was employed to study the thermodynamic parameters of weak interactions between aqueous cesium chloride and the monosaccharides (D-glucose, D-galactose, D-xylose, and D-arabinose) at T = 298.15 K. Activity coefficients for this system obtained from electromotive force measurements indicate that they have a close relationship with the stereostructure of the saccharide. The Gibbs free energy pair interaction parameters and salting constants were also evaluated; these can characterize the interaction between the saccharides and CsCl in water. The results were interpreted on the basis of a model of structural and electrostatic interaction and the hydration effect of the hydroxyl ion of these saccharides. (C) 2002 Elsevier Science Ltd. All rights reserved.
KeywordThermodynamic Parameter Cscl Monosaccharide Ion Selective Electrode
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordTRIVALENT LANTHANIDE CATIONS ; 278.15-318.15 K ; ACTIVITY-COEFFICIENTS ; AQUEOUS-SOLUTIONS ; HEAT-CAPACITIES ; NACL ; HCL ; SYSTEMS ; SUGARS ; COMPLEXATION
Indexed BySCI
Language英语
WOS Research AreaThermodynamics ; Chemistry
WOS SubjectThermodynamics ; Chemistry, Physical
WOS IDWOS:000179963900004
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6070
Collection青海盐湖研究所知识仓储
Affiliation1.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Peoples R China
2.Henan Normal Univ, Sch Chem & Environm Sci, Henan 453002, Peoples R China
3.Shaanxi Normal Univ, Sch Chem & Mat Sci, Shaanxi 710062, Peoples R China
Recommended Citation
GB/T 7714
Jiang, YC,Gao, SY,Xia, SP,et al. Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2002,34(12):1959-1973.
APA Jiang, YC,Gao, SY,Xia, SP,Wang, JJ,Zhuo, KL,&Hu, MC.(2002).Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K.JOURNAL OF CHEMICAL THERMODYNAMICS,34(12),1959-1973.
MLA Jiang, YC,et al."Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K".JOURNAL OF CHEMICAL THERMODYNAMICS 34.12(2002):1959-1973.
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