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Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K
Jiang, YC; Gao, SY; Xia, SP; Wang, JJ; Zhuo, KL; Hu, MC
2002-12-01
发表期刊JOURNAL OF CHEMICAL THERMODYNAMICS
卷号34期号:12页码:1959-1973
文章类型Article
摘要A non-liquid-junction electrochemical cell composed of a potassium ion selective electrode(K-ISE) against a chloride ion selective electrode (Cl-ISE) as a reference electrode was employed to study the thermodynamic parameters of weak interactions between aqueous cesium chloride and the monosaccharides (D-glucose, D-galactose, D-xylose, and D-arabinose) at T = 298.15 K. Activity coefficients for this system obtained from electromotive force measurements indicate that they have a close relationship with the stereostructure of the saccharide. The Gibbs free energy pair interaction parameters and salting constants were also evaluated; these can characterize the interaction between the saccharides and CsCl in water. The results were interpreted on the basis of a model of structural and electrostatic interaction and the hydration effect of the hydroxyl ion of these saccharides. (C) 2002 Elsevier Science Ltd. All rights reserved.
关键词Thermodynamic Parameter Cscl Monosaccharide Ion Selective Electrode
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]TRIVALENT LANTHANIDE CATIONS ; 278.15-318.15 K ; ACTIVITY-COEFFICIENTS ; AQUEOUS-SOLUTIONS ; HEAT-CAPACITIES ; NACL ; HCL ; SYSTEMS ; SUGARS ; COMPLEXATION
收录类别SCI
语种英语
WOS研究方向Thermodynamics ; Chemistry
WOS类目Thermodynamics ; Chemistry, Physical
WOS记录号WOS:000179963900004
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6070
专题青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Peoples R China
2.Henan Normal Univ, Sch Chem & Environm Sci, Henan 453002, Peoples R China
3.Shaanxi Normal Univ, Sch Chem & Mat Sci, Shaanxi 710062, Peoples R China
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GB/T 7714
Jiang, YC,Gao, SY,Xia, SP,et al. Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2002,34(12):1959-1973.
APA Jiang, YC,Gao, SY,Xia, SP,Wang, JJ,Zhuo, KL,&Hu, MC.(2002).Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K.JOURNAL OF CHEMICAL THERMODYNAMICS,34(12),1959-1973.
MLA Jiang, YC,et al."Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K".JOURNAL OF CHEMICAL THERMODYNAMICS 34.12(2002):1959-1973.
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