Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K

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	Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K
	Jiang, YC ; Gao, SY ; Xia, SP ; Wang, JJ ; Zhuo, KL ; Hu, MC
	2002-12-01
发表期刊	JOURNAL OF CHEMICAL THERMODYNAMICS
卷号	34 期号:12 页码:1959-1973
关键词	Thermodynamic Parameter Cscl Monosaccharide Ion Selective Electrode
摘要	A non-liquid-junction electrochemical cell composed of a potassium ion selective electrode(K-ISE) against a chloride ion selective electrode (Cl-ISE) as a reference electrode was employed to study the thermodynamic parameters of weak interactions between aqueous cesium chloride and the monosaccharides (D-glucose, D-galactose, D-xylose, and D-arabinose) at T = 298.15 K. Activity coefficients for this system obtained from electromotive force measurements indicate that they have a close relationship with the stereostructure of the saccharide. The Gibbs free energy pair interaction parameters and salting constants were also evaluated; these can characterize the interaction between the saccharides and CsCl in water. The results were interpreted on the basis of a model of structural and electrostatic interaction and the hydration effect of the hydroxyl ion of these saccharides. (C) 2002 Elsevier Science Ltd. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/6070
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Peoples R China 2.Henan Normal Univ, Sch Chem & Environm Sci, Henan 453002, Peoples R China 3.Shaanxi Normal Univ, Sch Chem & Mat Sci, Shaanxi 710062, Peoples R China
推荐引用方式 GB/T 7714	Jiang, YC,Gao, SY,Xia, SP,et al. Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2002,34(12):1959-1973.
APA	Jiang, YC,Gao, SY,Xia, SP,Wang, JJ,Zhuo, KL,&Hu, MC.(2002).Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K.JOURNAL OF CHEMICAL THERMODYNAMICS,34(12),1959-1973.
MLA	Jiang, YC,et al."Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K".JOURNAL OF CHEMICAL THERMODYNAMICS 34.12(2002):1959-1973.