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Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O
Yue, T; Gao, SY; Zhu, LX; Xia, SP; Yu, KB
2002-10-01
发表期刊JOURNAL OF MOLECULAR STRUCTURE
卷号616期号:1-3页码:247-252
文章类型Article
摘要The crystal of magnesium oxysulfate hydrate 2MgSO(4).Mg(OH)(2).2H(2)O was synthesized in MgSO4 and NaOH solutions at 160 T for 21 days and its structure has been determined to be orthorhombic system space group Pbcm with cell data: a = 7.177(1) Angstrom, b = 9.804(2) Angstrom, c = 12.775(2) Angstrom, beta = 90degrees, and Z = 4; Dc = 2.476 g cm(-3), mu = 0.869 mm(-1), F(000) = 680. The structure was solved by full-matrix least-squares on methods and refined to R = 0.0371, wR = 0.0724 using 1036 independent reflections measured with a X-ray diffraction technology. The structure consists of straight chains of face-sharing Mg2+ is at their centers. The Mg atom coordinated around O atom SO4 in another layer to form a multi-layer structure crystal. The thermal analytical curve of this compound was recorded and its decomposition mechanism was discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
关键词Magnesium Oxysulfate Crystal Growth Crystal Structure Spectra Thermal Analysis
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]HYDROXIDE-SULFATE-HYDRATE ; CAMINITE
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000178091200027
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6076
专题青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
2.Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Chengdu Branch, Chengdu 610041, Peoples R China
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GB/T 7714
Yue, T,Gao, SY,Zhu, LX,et al. Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O[J]. JOURNAL OF MOLECULAR STRUCTURE,2002,616(1-3):247-252.
APA Yue, T,Gao, SY,Zhu, LX,Xia, SP,&Yu, KB.(2002).Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O.JOURNAL OF MOLECULAR STRUCTURE,616(1-3),247-252.
MLA Yue, T,et al."Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O".JOURNAL OF MOLECULAR STRUCTURE 616.1-3(2002):247-252.
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