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Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O
Yue, T; Gao, SY; Zhu, LX; Xia, SP; Yu, KB
2002-10-01
Source PublicationJOURNAL OF MOLECULAR STRUCTURE
Volume616Issue:1-3Pages:247-252
SubtypeArticle
AbstractThe crystal of magnesium oxysulfate hydrate 2MgSO(4).Mg(OH)(2).2H(2)O was synthesized in MgSO4 and NaOH solutions at 160 T for 21 days and its structure has been determined to be orthorhombic system space group Pbcm with cell data: a = 7.177(1) Angstrom, b = 9.804(2) Angstrom, c = 12.775(2) Angstrom, beta = 90degrees, and Z = 4; Dc = 2.476 g cm(-3), mu = 0.869 mm(-1), F(000) = 680. The structure was solved by full-matrix least-squares on methods and refined to R = 0.0371, wR = 0.0724 using 1036 independent reflections measured with a X-ray diffraction technology. The structure consists of straight chains of face-sharing Mg2+ is at their centers. The Mg atom coordinated around O atom SO4 in another layer to form a multi-layer structure crystal. The thermal analytical curve of this compound was recorded and its decomposition mechanism was discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
KeywordMagnesium Oxysulfate Crystal Growth Crystal Structure Spectra Thermal Analysis
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordHYDROXIDE-SULFATE-HYDRATE ; CAMINITE
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000178091200027
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6076
Collection青海盐湖研究所知识仓储
Affiliation1.Chinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
2.Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Chengdu Branch, Chengdu 610041, Peoples R China
Recommended Citation
GB/T 7714
Yue, T,Gao, SY,Zhu, LX,et al. Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O[J]. JOURNAL OF MOLECULAR STRUCTURE,2002,616(1-3):247-252.
APA Yue, T,Gao, SY,Zhu, LX,Xia, SP,&Yu, KB.(2002).Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O.JOURNAL OF MOLECULAR STRUCTURE,616(1-3),247-252.
MLA Yue, T,et al."Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O".JOURNAL OF MOLECULAR STRUCTURE 616.1-3(2002):247-252.
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