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Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O
Yue, T; Gao, SY; Zhu, LX; Xia, SP; Yu, KB
2002-10-01
发表期刊JOURNAL OF MOLECULAR STRUCTURE
卷号616期号:1-3页码:247-252
关键词Magnesium Oxysulfate Crystal Growth Crystal Structure Spectra Thermal Analysis
摘要The crystal of magnesium oxysulfate hydrate 2MgSO(4).Mg(OH)(2).2H(2)O was synthesized in MgSO4 and NaOH solutions at 160 T for 21 days and its structure has been determined to be orthorhombic system space group Pbcm with cell data: a = 7.177(1) Angstrom, b = 9.804(2) Angstrom, c = 12.775(2) Angstrom, beta = 90degrees, and Z = 4; Dc = 2.476 g cm(-3), mu = 0.869 mm(-1), F(000) = 680. The structure was solved by full-matrix least-squares on methods and refined to R = 0.0371, wR = 0.0724 using 1036 independent reflections measured with a X-ray diffraction technology. The structure consists of straight chains of face-sharing Mg2+ is at their centers. The Mg atom coordinated around O atom SO4 in another layer to form a multi-layer structure crystal. The thermal analytical curve of this compound was recorded and its decomposition mechanism was discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6076
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Chinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
2.Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Chengdu Branch, Chengdu 610041, Peoples R China
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GB/T 7714
Yue, T,Gao, SY,Zhu, LX,et al. Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O[J]. JOURNAL OF MOLECULAR STRUCTURE,2002,616(1-3):247-252.
APA Yue, T,Gao, SY,Zhu, LX,Xia, SP,&Yu, KB.(2002).Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O.JOURNAL OF MOLECULAR STRUCTURE,616(1-3),247-252.
MLA Yue, T,et al."Crystal growth and crystal structure of magnesium oxysulfate 2MgSO(4)(.)Mg(OH)(2)(.)2H(2)O".JOURNAL OF MOLECULAR STRUCTURE 616.1-3(2002):247-252.
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