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FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution
Liu, ZH; Gao, B; Hu, MC; Li, S; Xia, SP
2003-10-01
Source PublicationSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume59Issue:12Pages:2741-2745
SubtypeArticle
AbstractHydrated cesium borates have been synthesized by the reaction Of CS2CO3 with H3BO3 aqueous solution. After reaction equilibria were reached, liquid and solid phases were separated and the FT-IR difference and Raman spectra of each phase were recorded, respectively. The assignments of the recorded FT-IR absorption frequencies and Raman shift are given. The main polyborate anions and their interaction in borate aqueous solution have been proposed. The relations between the existing forms of polyborate anions and the crystallizing solid phases, Cs(2)B(4)O(7)(.)5H(2)O and CsB(5)O(8)(.)4H(2)O, have been gained. (C) 2003 Elsevier Science B.V. All rights reserved.
KeywordFt-ir Difference Spectra Raman Spectra Hydrated Cesium Borates Saturated Aqueous Solution
WOS HeadingsScience & Technology ; Technology
Indexed BySCI
Language英语
WOS Research AreaSpectroscopy
WOS SubjectSpectroscopy
WOS IDWOS:000185719600008
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6090
Collection青海盐湖研究所知识仓储
Affiliation1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
2.Acad Sinica, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
Recommended Citation
GB/T 7714
Liu, ZH,Gao, B,Hu, MC,et al. FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2003,59(12):2741-2745.
APA Liu, ZH,Gao, B,Hu, MC,Li, S,&Xia, SP.(2003).FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,59(12),2741-2745.
MLA Liu, ZH,et al."FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 59.12(2003):2741-2745.
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