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FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution
Liu, ZH; Gao, B; Hu, MC; Li, S; Xia, SP
2003-10-01
发表期刊SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷号59期号:12页码:2741-2745
文章类型Article
摘要Hydrated cesium borates have been synthesized by the reaction Of CS2CO3 with H3BO3 aqueous solution. After reaction equilibria were reached, liquid and solid phases were separated and the FT-IR difference and Raman spectra of each phase were recorded, respectively. The assignments of the recorded FT-IR absorption frequencies and Raman shift are given. The main polyborate anions and their interaction in borate aqueous solution have been proposed. The relations between the existing forms of polyborate anions and the crystallizing solid phases, Cs(2)B(4)O(7)(.)5H(2)O and CsB(5)O(8)(.)4H(2)O, have been gained. (C) 2003 Elsevier Science B.V. All rights reserved.
关键词Ft-ir Difference Spectra Raman Spectra Hydrated Cesium Borates Saturated Aqueous Solution
WOS标题词Science & Technology ; Technology
收录类别SCI
语种英语
WOS研究方向Spectroscopy
WOS类目Spectroscopy
WOS记录号WOS:000185719600008
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6090
专题青海盐湖研究所知识仓储
作者单位1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
2.Acad Sinica, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
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GB/T 7714
Liu, ZH,Gao, B,Hu, MC,et al. FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2003,59(12):2741-2745.
APA Liu, ZH,Gao, B,Hu, MC,Li, S,&Xia, SP.(2003).FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,59(12),2741-2745.
MLA Liu, ZH,et al."FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 59.12(2003):2741-2745.
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