FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution

ISL OpenIR > 青海盐湖研究所知识仓储

	FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution
	Liu, ZH ; Gao, B ; Hu, MC ; Li, S ; Xia, SP
	2003-10-01
发表期刊	SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷号	59 期号:12 页码:2741-2745
关键词	Ft-ir Difference Spectra Raman Spectra Hydrated Cesium Borates Saturated Aqueous Solution
摘要	Hydrated cesium borates have been synthesized by the reaction Of CS2CO3 with H3BO3 aqueous solution. After reaction equilibria were reached, liquid and solid phases were separated and the FT-IR difference and Raman spectra of each phase were recorded, respectively. The assignments of the recorded FT-IR absorption frequencies and Raman shift are given. The main polyborate anions and their interaction in borate aqueous solution have been proposed. The relations between the existing forms of polyborate anions and the crystallizing solid phases, Cs(2)B(4)O(7)(.)5H(2)O and CsB(5)O(8)(.)4H(2)O, have been gained. (C) 2003 Elsevier Science B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/6090
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China 2.Acad Sinica, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
推荐引用方式 GB/T 7714	Liu, ZH,Gao, B,Hu, MC,et al. FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2003,59(12):2741-2745.
APA	Liu, ZH,Gao, B,Hu, MC,Li, S,&Xia, SP.(2003).FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,59(12),2741-2745.
MLA	Liu, ZH,et al."FT-IR and Raman spectroscopic analysis of hydrated cesium borates and their saturated aqueous solution".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 59.12(2003):2741-2745.