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Thermochemistry of tetrahydrated rubidium pentaborate
Zhu, LX; Yue, T; Gao, SY; Xia, SP
2003-03-01
发表期刊JOURNAL OF CHEMICAL THERMODYNAMICS
卷号35期号:3页码:433-438
文章类型Article
摘要The enthalpies of solution of RbB5O8 . 4H(2)O in approximately 1 mol . dm(-3) aqueous hydrochloric acid and of RbCl in aqueous (hydrochloric acid+boric acid) were determined. From these results and the enthalpy of solution of H3BO3 in approximately 1 mol . dm(-3) HCl(aq), the standard molar enthalpy of formation of -(4837.27 +/- 4.03)kJ . mol(-1) for RbB5O8 . 4H(2)O was obtained from the standard molar enthalpies of formation of RbCl(s), H3BO3 (s), and H2O(1). The standard molar entropy of formation of RbB5O8 . 4H(2)O was calculated from the thermodynamic relation with the standard molar Gibbs free energy of forrnation of RbB5O8. 4H(2)O computed from a group contribution method. (C) 2003 Elsevier Science Ltd. All rights reserved.
关键词Rbb5o8 Center Dot 4h(2)o Standard Molar Enthalpy Of Formation Solution Calorimetry Molar Enthalpy Of Solution Aqueous Hydrochloric Acid Solution
WOS标题词Science & Technology ; Physical Sciences
收录类别SCI
语种英语
WOS研究方向Thermodynamics ; Chemistry
WOS类目Thermodynamics ; Chemistry, Physical
WOS记录号WOS:000181782300005
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6091
专题青海盐湖研究所知识仓储
作者单位Acad Sinica, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
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Zhu, LX,Yue, T,Gao, SY,et al. Thermochemistry of tetrahydrated rubidium pentaborate[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2003,35(3):433-438.
APA Zhu, LX,Yue, T,Gao, SY,&Xia, SP.(2003).Thermochemistry of tetrahydrated rubidium pentaborate.JOURNAL OF CHEMICAL THERMODYNAMICS,35(3),433-438.
MLA Zhu, LX,et al."Thermochemistry of tetrahydrated rubidium pentaborate".JOURNAL OF CHEMICAL THERMODYNAMICS 35.3(2003):433-438.
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