ISL OpenIR  > 青海盐湖研究所知识仓储
Crystal structure and thermal behavior of Rb2Co[B6O7(OH)(6)](2)center dot 4H(2)O
Yue, T; Zhu, LX; Xia, SP; Gao, SY; Yu, KB
2003-08-25
Source PublicationJOURNAL OF ALLOYS AND COMPOUNDS
Volume358Issue:1-2Pages:87-92
SubtypeArticle
AbstractA crystal of the complex borate Rb2Co[B6O7(OH)(6)](2).4H(2)O was synthesized in the molar ratio Rb2O/CoCl2/B2O3=4:1:9, and its structure was determined by single-crystal X-ray diffraction. It belongs to the P (1) over bar triclinic space group, with the following unit cell parameters: a = 7.549(1) Angstrom, b = 7.872(1) Angstrom, c = 10.980(2) Angstrom, alpha = 107.87(1)degrees, beta = 94.83(1)degrees, gamma = 90.27(1)degrees, Z = 2, V = 618.45(19) Angstrom(3). The crystal structure was solved from 2162 independent reflections until R = 0.0127. The crystal structure of Rb2Co[B6O7(OH)(6)](2).4H(2)O consists of [B6O7(OH)(6)](2-) polyborate anions, Co-O octahedra and Rb-O polyhedra. The isolated [B6O7(OH)(6)](2) polyborate anions are separated by free water molecules and Rb and Co cations. Dehydration of this hydrated mixed borate Occurs in two steps and leads to an amorphous phase which undergoes crystallization. (C) 2003 Elsevier B.V. All rights reserved.
KeywordTransition Metal Compounds Chemical Synthesis Crystal Structure X-ray Diffraction
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS KeywordNONLINEAR-OPTICAL CRYSTAL
Indexed BySCI
Language英语
WOS Research AreaChemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000185147000018
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6094
Collection青海盐湖研究所知识仓储
Affiliation1.Chinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
2.Chinese Acad Sci, Chengdu Branch, Chengdu 610041, Peoples R China
Recommended Citation
GB/T 7714
Yue, T,Zhu, LX,Xia, SP,et al. Crystal structure and thermal behavior of Rb2Co[B6O7(OH)(6)](2)center dot 4H(2)O[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2003,358(1-2):87-92.
APA Yue, T,Zhu, LX,Xia, SP,Gao, SY,&Yu, KB.(2003).Crystal structure and thermal behavior of Rb2Co[B6O7(OH)(6)](2)center dot 4H(2)O.JOURNAL OF ALLOYS AND COMPOUNDS,358(1-2),87-92.
MLA Yue, T,et al."Crystal structure and thermal behavior of Rb2Co[B6O7(OH)(6)](2)center dot 4H(2)O".JOURNAL OF ALLOYS AND COMPOUNDS 358.1-2(2003):87-92.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yue, T]'s Articles
[Zhu, LX]'s Articles
[Xia, SP]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yue, T]'s Articles
[Zhu, LX]'s Articles
[Xia, SP]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yue, T]'s Articles
[Zhu, LX]'s Articles
[Xia, SP]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.