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The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K
Jiang, YC; Gao, SY; Xia, SP; Hu, MC; Wang, JJ; Lu, Y; Zhuo, KL
2003-04-17
发表期刊THERMOCHIMICA ACTA
卷号400期号:1-2页码:37-42
文章类型Article
摘要The transfer enthalpies have been measured for cesium chloride from pure water to aqueous saccharides (D-glucose, D-fructose and sucrose) solutions at 298.15 K. The McMillan-Mayer theory was employed to relate the excess thermodynamic function with a series of interaction parameters of solutes to obtain the enthalpy pair interaction parameters of cesium chloride with saccharides in water. Entropy interaction parameters can be evaluated through the enthalpy interaction parameters and the Gibbs free energy parameters. These parameters are discussed in detail to provide some information for the interaction of solute-solute and solute-solvent in CsCl-saccharide-water ternary system, and to investigate the influence of the size of metal ions and the number of hydroxyl in saccharides on these parameters. (C) 2002 Elsevier Science B.V. All rights reserved.
关键词Cesium Chloride Saccharides Enthalpy And Entropy Interaction Parameters
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]HEAT-CAPACITIES ; VOLUMES ; HALIDES ; BINDING ; UREA
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Analytical ; Chemistry, Physical
WOS记录号WOS:000182494100004
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6095
专题青海盐湖研究所知识仓储
作者单位1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xian 710043, Shaanxi, Peoples R China
3.Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453002, Henan, Peoples R China
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Jiang, YC,Gao, SY,Xia, SP,et al. The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K[J]. THERMOCHIMICA ACTA,2003,400(1-2):37-42.
APA Jiang, YC.,Gao, SY.,Xia, SP.,Hu, MC.,Wang, JJ.,...&Zhuo, KL.(2003).The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K.THERMOCHIMICA ACTA,400(1-2),37-42.
MLA Jiang, YC,et al."The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K".THERMOCHIMICA ACTA 400.1-2(2003):37-42.
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