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The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K
Jiang, YC; Gao, SY; Xia, SP; Hu, MC; Wang, JJ; Lu, Y; Zhuo, KL
2003-04-17
Source PublicationTHERMOCHIMICA ACTA
Volume400Issue:1-2Pages:37-42
SubtypeArticle
AbstractThe transfer enthalpies have been measured for cesium chloride from pure water to aqueous saccharides (D-glucose, D-fructose and sucrose) solutions at 298.15 K. The McMillan-Mayer theory was employed to relate the excess thermodynamic function with a series of interaction parameters of solutes to obtain the enthalpy pair interaction parameters of cesium chloride with saccharides in water. Entropy interaction parameters can be evaluated through the enthalpy interaction parameters and the Gibbs free energy parameters. These parameters are discussed in detail to provide some information for the interaction of solute-solute and solute-solvent in CsCl-saccharide-water ternary system, and to investigate the influence of the size of metal ions and the number of hydroxyl in saccharides on these parameters. (C) 2002 Elsevier Science B.V. All rights reserved.
KeywordCesium Chloride Saccharides Enthalpy And Entropy Interaction Parameters
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordHEAT-CAPACITIES ; VOLUMES ; HALIDES ; BINDING ; UREA
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Analytical ; Chemistry, Physical
WOS IDWOS:000182494100004
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6095
Collection青海盐湖研究所知识仓储
Affiliation1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xian 710043, Shaanxi, Peoples R China
3.Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453002, Henan, Peoples R China
Recommended Citation
GB/T 7714
Jiang, YC,Gao, SY,Xia, SP,et al. The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K[J]. THERMOCHIMICA ACTA,2003,400(1-2):37-42.
APA Jiang, YC.,Gao, SY.,Xia, SP.,Hu, MC.,Wang, JJ.,...&Zhuo, KL.(2003).The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K.THERMOCHIMICA ACTA,400(1-2),37-42.
MLA Jiang, YC,et al."The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K".THERMOCHIMICA ACTA 400.1-2(2003):37-42.
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