The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K

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	The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K
	Jiang, YC ; Gao, SY ; Xia, SP ; Hu, MC ; Wang, JJ ; Lu, Y ; Zhuo, KL
	2003-04-17
发表期刊	THERMOCHIMICA ACTA
卷号	400 期号:1-2 页码:37-42
关键词	Cesium Chloride Saccharides Enthalpy And Entropy Interaction Parameters
摘要	The transfer enthalpies have been measured for cesium chloride from pure water to aqueous saccharides (D-glucose, D-fructose and sucrose) solutions at 298.15 K. The McMillan-Mayer theory was employed to relate the excess thermodynamic function with a series of interaction parameters of solutes to obtain the enthalpy pair interaction parameters of cesium chloride with saccharides in water. Entropy interaction parameters can be evaluated through the enthalpy interaction parameters and the Gibbs free energy parameters. These parameters are discussed in detail to provide some information for the interaction of solute-solute and solute-solvent in CsCl-saccharide-water ternary system, and to investigate the influence of the size of metal ions and the number of hydroxyl in saccharides on these parameters. (C) 2002 Elsevier Science B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/6095
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xian 710043, Shaanxi, Peoples R China 3.Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453002, Henan, Peoples R China
推荐引用方式 GB/T 7714	Jiang, YC,Gao, SY,Xia, SP,et al. The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K[J]. THERMOCHIMICA ACTA,2003,400(1-2):37-42.
APA	Jiang, YC.,Gao, SY.,Xia, SP.,Hu, MC.,Wang, JJ.,...&Zhuo, KL.(2003).The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K.THERMOCHIMICA ACTA,400(1-2),37-42.
MLA	Jiang, YC,et al."The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K".THERMOCHIMICA ACTA 400.1-2(2003):37-42.