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Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K
Jiang, YC; Gao, SY; Xia, SP; Wang, JJ; Zhuo, KL; Hu, MC
2003-10-01
Source PublicationJOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume50Issue:5Pages:947-952
SubtypeArticle
AbstractDensities have been measured for the CsCl-saccharide (D-glucose, D-fructose)-water systems at 298.15 K. These data were used to calculate the apparent molar volume of CsCl ( V-Phi,V-E) and the saccharides (V-Phi,V-S), and the infinite dilution apparent molar volume V-Phi,E(0) and V-Phi,S(0) in the studied solutions. In addition, the standard transfer volume Delta(t)V(phi,E)(0) of CsCl from water to aqueous saccharides solutions, and Delta(t)V(phi,S)(0) of saccharides from water to CsCl solutions have been evaluated and discussed using the structural interaction model. The volumetric interaction parameters for CsCl with saccharide in water were obtained and analyzed by the group additivity principle and the stereochemistry of the saccharide molecules.
KeywordDensity Apparent Molar Volume Standard Transfer Volume Volumetric Interaction Parameter Cscl Saccharide
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordAPPARENT MOLAR VOLUMES ; AQUEOUS-SOLUTIONS ; HEAT-CAPACITIES ; STEREOCHEMICAL ASPECTS ; EXCESS-ENTHALPIES ; WATER ; HYDRATION ; SUGARS ; MONOSACCHARIDES ; THERMODYNAMICS
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000186578700002
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6097
Collection青海盐湖研究所知识仓储
Affiliation1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
2.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Shaanxi, Peoples R China
3.Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453002, Henan, Peoples R China
Recommended Citation
GB/T 7714
Jiang, YC,Gao, SY,Xia, SP,et al. Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY,2003,50(5):947-952.
APA Jiang, YC,Gao, SY,Xia, SP,Wang, JJ,Zhuo, KL,&Hu, MC.(2003).Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K.JOURNAL OF THE CHINESE CHEMICAL SOCIETY,50(5),947-952.
MLA Jiang, YC,et al."Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K".JOURNAL OF THE CHINESE CHEMICAL SOCIETY 50.5(2003):947-952.
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