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Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K
Jiang, YC; Gao, SY; Xia, SP; Wang, JJ; Zhuo, KL; Hu, MC
2003-10-01
发表期刊JOURNAL OF THE CHINESE CHEMICAL SOCIETY
卷号50期号:5页码:947-952
文章类型Article
摘要Densities have been measured for the CsCl-saccharide (D-glucose, D-fructose)-water systems at 298.15 K. These data were used to calculate the apparent molar volume of CsCl ( V-Phi,V-E) and the saccharides (V-Phi,V-S), and the infinite dilution apparent molar volume V-Phi,E(0) and V-Phi,S(0) in the studied solutions. In addition, the standard transfer volume Delta(t)V(phi,E)(0) of CsCl from water to aqueous saccharides solutions, and Delta(t)V(phi,S)(0) of saccharides from water to CsCl solutions have been evaluated and discussed using the structural interaction model. The volumetric interaction parameters for CsCl with saccharide in water were obtained and analyzed by the group additivity principle and the stereochemistry of the saccharide molecules.
关键词Density Apparent Molar Volume Standard Transfer Volume Volumetric Interaction Parameter Cscl Saccharide
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]APPARENT MOLAR VOLUMES ; AQUEOUS-SOLUTIONS ; HEAT-CAPACITIES ; STEREOCHEMICAL ASPECTS ; EXCESS-ENTHALPIES ; WATER ; HYDRATION ; SUGARS ; MONOSACCHARIDES ; THERMODYNAMICS
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000186578700002
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6097
专题青海盐湖研究所知识仓储
作者单位1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
2.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Shaanxi, Peoples R China
3.Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453002, Henan, Peoples R China
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GB/T 7714
Jiang, YC,Gao, SY,Xia, SP,et al. Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY,2003,50(5):947-952.
APA Jiang, YC,Gao, SY,Xia, SP,Wang, JJ,Zhuo, KL,&Hu, MC.(2003).Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K.JOURNAL OF THE CHINESE CHEMICAL SOCIETY,50(5),947-952.
MLA Jiang, YC,et al."Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K".JOURNAL OF THE CHINESE CHEMICAL SOCIETY 50.5(2003):947-952.
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