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Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K
Jiang, YC; Wang, JJ; Zhuo, KL; Gao, SY; Xia, SP; Hu, MC
2003-10-10
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
Volume24Issue:10Pages:1842-1846
SubtypeArticle
AbstractElectrochemical cells with a potassium ion selectivity electrode (Na-ISE) as a measuring electrode versus a chloride ion selectivity electrode as a reference electrode (Cl-ISE) were used to investigate the interaction of solute-solute and solute-solvent in the CsCl-saccharide(D-glucose, D-fructose and sucrose)-, water ternary system at 298.15 K. The activity coefficients of CsCl in saccharides aqueous solutions can be determined through the measurements of electromotive force, and the activity coefficients of saccharides in CsCl aqueous solutions can be evaluated in terms of the Scatchard theory. The McMillan-Mayer theory is employed to relate the excess thermodynamic function with a series of interaction parameters of solute in water so as to obtain the pair Gibbs free energy interaction parameters and salting constant. These parameters have been analyzed by using the model of structural interaction, the effect of hydration of hydroxyl of saccharide and the theory of dispersion energy and the stereostructure of saccharides, which indicates that the interactions of these saccharides with CsCl are controlled mostly by the structure and conformation of their molecules in water.
KeywordCscl Glucose Fructose Sucrose Weak Interaction Thermodynamic Parameters
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordTRIVALENT LANTHANIDE CATIONS ; ACTIVITY-COEFFICIENTS ; AQUEOUS-SOLUTIONS ; SYSTEMS ; NACL ; 25-DEGREES-C ; COMPLEXATION ; ALDITOLS ; MIXTURES ; BINDING
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000186135000029
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6101
Collection青海盐湖研究所知识仓储
Affiliation1.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Peoples R China
2.Henan Normal Univ, Xinxiang 4530023, Peoples R China
3.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China
Recommended Citation
GB/T 7714
Jiang, YC,Wang, JJ,Zhuo, KL,et al. Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,24(10):1842-1846.
APA Jiang, YC,Wang, JJ,Zhuo, KL,Gao, SY,Xia, SP,&Hu, MC.(2003).Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,24(10),1842-1846.
MLA Jiang, YC,et al."Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 24.10(2003):1842-1846.
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