ISL OpenIR  > 青海盐湖研究所知识仓储
Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K
Jiang, YC; Wang, JJ; Zhuo, KL; Gao, SY; Xia, SP; Hu, MC
2003-10-10
发表期刊CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
卷号24期号:10页码:1842-1846
文章类型Article
摘要Electrochemical cells with a potassium ion selectivity electrode (Na-ISE) as a measuring electrode versus a chloride ion selectivity electrode as a reference electrode (Cl-ISE) were used to investigate the interaction of solute-solute and solute-solvent in the CsCl-saccharide(D-glucose, D-fructose and sucrose)-, water ternary system at 298.15 K. The activity coefficients of CsCl in saccharides aqueous solutions can be determined through the measurements of electromotive force, and the activity coefficients of saccharides in CsCl aqueous solutions can be evaluated in terms of the Scatchard theory. The McMillan-Mayer theory is employed to relate the excess thermodynamic function with a series of interaction parameters of solute in water so as to obtain the pair Gibbs free energy interaction parameters and salting constant. These parameters have been analyzed by using the model of structural interaction, the effect of hydration of hydroxyl of saccharide and the theory of dispersion energy and the stereostructure of saccharides, which indicates that the interactions of these saccharides with CsCl are controlled mostly by the structure and conformation of their molecules in water.
关键词Cscl Glucose Fructose Sucrose Weak Interaction Thermodynamic Parameters
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]TRIVALENT LANTHANIDE CATIONS ; ACTIVITY-COEFFICIENTS ; AQUEOUS-SOLUTIONS ; SYSTEMS ; NACL ; 25-DEGREES-C ; COMPLEXATION ; ALDITOLS ; MIXTURES ; BINDING
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000186135000029
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6101
专题青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Peoples R China
2.Henan Normal Univ, Xinxiang 4530023, Peoples R China
3.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China
推荐引用方式
GB/T 7714
Jiang, YC,Wang, JJ,Zhuo, KL,et al. Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,24(10):1842-1846.
APA Jiang, YC,Wang, JJ,Zhuo, KL,Gao, SY,Xia, SP,&Hu, MC.(2003).Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,24(10),1842-1846.
MLA Jiang, YC,et al."Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 24.10(2003):1842-1846.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Jiang, YC]的文章
[Wang, JJ]的文章
[Zhuo, KL]的文章
百度学术
百度学术中相似的文章
[Jiang, YC]的文章
[Wang, JJ]的文章
[Zhuo, KL]的文章
必应学术
必应学术中相似的文章
[Jiang, YC]的文章
[Wang, JJ]的文章
[Zhuo, KL]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。