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Preparation and studies on the thermodynamic and kinetic properties of lithium intercalation of Li2.6C0.4N material
Zhou, Y; Jian, YZ; Yan, JM; Yang, JX; Wang, ZC; Jing, Y
2003-12-01
发表期刊CHINESE JOURNAL OF INORGANIC CHEMISTRY
卷号19期号:12页码:1307-1310
文章类型Article
摘要Under the circumstance of NH3, the new anode material Li2.6Co0.4N for lithium ion battery was prepared by using Li3N and Co powders as raw materials. The structure and the lithium intercalation properties were investigated by I means of XRD and coulombic titration. The results show that Li2.6Co0.4N has a hexagonal structure with the unit cell parameters: a = 0. 500 nm, c = 0. 387 nm; Its capacity is 829 mAh . g(-1). The maximum intercalation of Li+ is 1.7215. The intercalation free energy (DeltaG(in)) of Li+ is -223.98 kj . mol(-1). The value of Li-ion electrochemical diffusion coefficient (D) is 4.6 x 10(-10) similar to 2.65 x 10(-9) cm(2) . s(-1). And also, a series of other thermodynamic and kinetic parameters were gained.
关键词Li2.6co0.4n Litium Ion intercalatIon Free Energy Li-ion Electrochemical Diffusion Coefficient Crystal Structure
WOS标题词Science & Technology ; Physical Sciences
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
WOS记录号WOS:000187026200007
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6109
专题青海盐湖研究所知识仓储
作者单位Chinese Acad Sci, Inst Salt Lake, Xining 810008, Peoples R China
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GB/T 7714
Zhou, Y,Jian, YZ,Yan, JM,et al. Preparation and studies on the thermodynamic and kinetic properties of lithium intercalation of Li2.6C0.4N material[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2003,19(12):1307-1310.
APA Zhou, Y,Jian, YZ,Yan, JM,Yang, JX,Wang, ZC,&Jing, Y.(2003).Preparation and studies on the thermodynamic and kinetic properties of lithium intercalation of Li2.6C0.4N material.CHINESE JOURNAL OF INORGANIC CHEMISTRY,19(12),1307-1310.
MLA Zhou, Y,et al."Preparation and studies on the thermodynamic and kinetic properties of lithium intercalation of Li2.6C0.4N material".CHINESE JOURNAL OF INORGANIC CHEMISTRY 19.12(2003):1307-1310.
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