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Liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO center dot nB(2)O(3)-18%MgSO4-H2O system at 0 degrees C
Guo, GJ; Gao, SY; Xia, SP; Zhu, LX; Wang, B
2003-09-01
发表期刊ACTA CHIMICA SINICA
卷号61期号:9页码:1434-1440
文章类型Article
摘要The liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO-nB(2)O(3)-18% MgSO4-H2O system at 0 degreesC was given. This result was based on investigation of the crystallization processes of MgO.nB(2)O(3)-18% MgSO4-H2O system at 0 degreesC, identification of the compositions of solid phases by physical method and chemical analysis, and determination of the thermodynanuic equilibrium point. There are four fields in this diagram, corresponding to H3BO3, MgO.2B(2)O(3).9H(2)O (Hungchaoite), MgO.3B(2)O(3).7.5H(2)O (Mcallisterite) and 2MgO.3B(2)O(3) .15H(2)O (Inderite), respectively. Th research results show that MgSO4 and MgCl2 have different influence on the crystallization of Mg-borates.
关键词Mg-borate Supersaturated Solution Thermodynamic Non-equilibrium State Phase Diagram Polyborate Anion
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]SALT LAKE BRINE ; CRYSTALLIZATION KINETICS ; SUPERSATURATED SOLUTION ; CHEMISTRY ; 20-DEGREES-C ; BORATE
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000188245700018
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6112
专题青海盐湖研究所知识仓储
作者单位Chinese Acad Sci, Inst Salt Lakes, Xian 710043, Peoples R China
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GB/T 7714
Guo, GJ,Gao, SY,Xia, SP,et al. Liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO center dot nB(2)O(3)-18%MgSO4-H2O system at 0 degrees C[J]. ACTA CHIMICA SINICA,2003,61(9):1434-1440.
APA Guo, GJ,Gao, SY,Xia, SP,Zhu, LX,&Wang, B.(2003).Liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO center dot nB(2)O(3)-18%MgSO4-H2O system at 0 degrees C.ACTA CHIMICA SINICA,61(9),1434-1440.
MLA Guo, GJ,et al."Liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO center dot nB(2)O(3)-18%MgSO4-H2O system at 0 degrees C".ACTA CHIMICA SINICA 61.9(2003):1434-1440.
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