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Liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO center dot nB(2)O(3)-18%MgSO4-H2O system at 0 degrees C
Guo, GJ; Gao, SY; Xia, SP; Zhu, LX; Wang, B
2003-09-01
Source PublicationACTA CHIMICA SINICA
Volume61Issue:9Pages:1434-1440
SubtypeArticle
AbstractThe liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO-nB(2)O(3)-18% MgSO4-H2O system at 0 degreesC was given. This result was based on investigation of the crystallization processes of MgO.nB(2)O(3)-18% MgSO4-H2O system at 0 degreesC, identification of the compositions of solid phases by physical method and chemical analysis, and determination of the thermodynanuic equilibrium point. There are four fields in this diagram, corresponding to H3BO3, MgO.2B(2)O(3).9H(2)O (Hungchaoite), MgO.3B(2)O(3).7.5H(2)O (Mcallisterite) and 2MgO.3B(2)O(3) .15H(2)O (Inderite), respectively. Th research results show that MgSO4 and MgCl2 have different influence on the crystallization of Mg-borates.
KeywordMg-borate Supersaturated Solution Thermodynamic Non-equilibrium State Phase Diagram Polyborate Anion
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordSALT LAKE BRINE ; CRYSTALLIZATION KINETICS ; SUPERSATURATED SOLUTION ; CHEMISTRY ; 20-DEGREES-C ; BORATE
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000188245700018
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6112
Collection青海盐湖研究所知识仓储
AffiliationChinese Acad Sci, Inst Salt Lakes, Xian 710043, Peoples R China
Recommended Citation
GB/T 7714
Guo, GJ,Gao, SY,Xia, SP,et al. Liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO center dot nB(2)O(3)-18%MgSO4-H2O system at 0 degrees C[J]. ACTA CHIMICA SINICA,2003,61(9):1434-1440.
APA Guo, GJ,Gao, SY,Xia, SP,Zhu, LX,&Wang, B.(2003).Liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO center dot nB(2)O(3)-18%MgSO4-H2O system at 0 degrees C.ACTA CHIMICA SINICA,61(9),1434-1440.
MLA Guo, GJ,et al."Liquid-solid phase diagram of thermodynamic non-equilibrium state of MgO center dot nB(2)O(3)-18%MgSO4-H2O system at 0 degrees C".ACTA CHIMICA SINICA 61.9(2003):1434-1440.
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