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Thermochemistry of hydrated lithium monoborates
Zhu, LX; Gao, SY; Xia, SP
2004-09-10
发表期刊THERMOCHIMICA ACTA
卷号419期号:1-2页码:105-108
文章类型Article
摘要The enthalpies of solution of two hydrated lithium monoborates in approximately 1 mol dm(-3) aqueous hydrochloric acid were determined. From these results and the enthalpies of solution of H3BO3 in approximately 1 mol dm(-3) HCl(aq), and of LiCl.H2O in aqueous(hydrochloric acid + boric acid),combining with the standard molar enthalpies of formation of LiCl.H2O(s), H3BO3(s) and H2O(1), the standard molar enthalpies of formation of -1627.46 +/- 0.90 and -3397.00 +/- 0.94 kJ mol(-1) for LiBO2.2H(2)O and LiBO2.8H(2)O were obtained. The standard molar entropies of formation of LiBO2.2H(2)O and LiBO2.8H(2)O were calculated from the thermodynamic relation with the standard molar Gibbs free energy of formation of LiBO2.2H(2)O and LiBO2.8H(2)O computed from a group contribution method. (C) 2004 Published by Elsevier B.V.
关键词Hydrated Lithium Monoborate Standard Molar Enthalpy Of Formation Solution Calorimetry Molar Enthalpy Of Solution Aqueous Hydrochloric Acid Solution
WOS标题词Science & Technology ; Physical Sciences
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Analytical ; Chemistry, Physical
WOS记录号WOS:000223762400013
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6116
专题青海盐湖研究所知识仓储
作者单位Chinese Acad Sci, Xian Branch, Inst Salt Lakes, Xian 710043, Shaanxi, Peoples R China
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Zhu, LX,Gao, SY,Xia, SP. Thermochemistry of hydrated lithium monoborates[J]. THERMOCHIMICA ACTA,2004,419(1-2):105-108.
APA Zhu, LX,Gao, SY,&Xia, SP.(2004).Thermochemistry of hydrated lithium monoborates.THERMOCHIMICA ACTA,419(1-2),105-108.
MLA Zhu, LX,et al."Thermochemistry of hydrated lithium monoborates".THERMOCHIMICA ACTA 419.1-2(2004):105-108.
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