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Thermochemistry of hydrated lithium monoborates
Zhu, LX; Gao, SY; Xia, SP
2004-09-10
Source PublicationTHERMOCHIMICA ACTA
Volume419Issue:1-2Pages:105-108
SubtypeArticle
AbstractThe enthalpies of solution of two hydrated lithium monoborates in approximately 1 mol dm(-3) aqueous hydrochloric acid were determined. From these results and the enthalpies of solution of H3BO3 in approximately 1 mol dm(-3) HCl(aq), and of LiCl.H2O in aqueous(hydrochloric acid + boric acid),combining with the standard molar enthalpies of formation of LiCl.H2O(s), H3BO3(s) and H2O(1), the standard molar enthalpies of formation of -1627.46 +/- 0.90 and -3397.00 +/- 0.94 kJ mol(-1) for LiBO2.2H(2)O and LiBO2.8H(2)O were obtained. The standard molar entropies of formation of LiBO2.2H(2)O and LiBO2.8H(2)O were calculated from the thermodynamic relation with the standard molar Gibbs free energy of formation of LiBO2.2H(2)O and LiBO2.8H(2)O computed from a group contribution method. (C) 2004 Published by Elsevier B.V.
KeywordHydrated Lithium Monoborate Standard Molar Enthalpy Of Formation Solution Calorimetry Molar Enthalpy Of Solution Aqueous Hydrochloric Acid Solution
WOS HeadingsScience & Technology ; Physical Sciences
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Analytical ; Chemistry, Physical
WOS IDWOS:000223762400013
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6116
Collection青海盐湖研究所知识仓储
AffiliationChinese Acad Sci, Xian Branch, Inst Salt Lakes, Xian 710043, Shaanxi, Peoples R China
Recommended Citation
GB/T 7714
Zhu, LX,Gao, SY,Xia, SP. Thermochemistry of hydrated lithium monoborates[J]. THERMOCHIMICA ACTA,2004,419(1-2):105-108.
APA Zhu, LX,Gao, SY,&Xia, SP.(2004).Thermochemistry of hydrated lithium monoborates.THERMOCHIMICA ACTA,419(1-2),105-108.
MLA Zhu, LX,et al."Thermochemistry of hydrated lithium monoborates".THERMOCHIMICA ACTA 419.1-2(2004):105-108.
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