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Study on the phase equilibrium of the ternary system ethanol-cesium carbonate-water at 10, 30 and 50 degrees C
Zhai, QG; Hu, MC; Liu, ZH; Xia, SP
2004
发表期刊CHINESE JOURNAL OF CHEMISTRY
卷号22期号:1页码:14-18
文章类型Article
摘要The phase diagrams of the CH3CH2OH-CS2CO3-H2O system were determined at 10, 30 and 50 degreesC, respectively. It was found that the effect of the temperature on the phase equilibrium was insignificant within the investigated range. The binodal curves were given using a five-parameter equation and the tie lines were fitted using the Othmer-Tobias and Bancroft correlations. Correlation coefficients (R) for all equations exceeded 0.99. Samples of the solid phase at 30 degreesC were analyzed by TGA showing that it consisted of CS2CO3 . 3.5H(2)O. The refractive index of the systems was also determined.
关键词Liquid-liquid Equilibrium Phase Diagram Cs2co3 Binadol Curve Tie Line
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]LIQUID-LIQUID EQUILIBRIUM ; SULFATE PLUS WATER ; POLY(ETHYLENE GLYCOL) ; AQUEOUS MIXTURES ; SOLID EQUILIBRIA ; 25-DEGREES-C ; 1-PROPANOL ; 2-PROPANOL ; DIAGRAMS ; MODEL
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000187998900004
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6128
专题青海盐湖研究所知识仓储
作者单位1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
2.Chinese Acad Sci, Inst Salt Lake, Xian Branch, Xian 710043, Shaanxi, Peoples R China
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GB/T 7714
Zhai, QG,Hu, MC,Liu, ZH,et al. Study on the phase equilibrium of the ternary system ethanol-cesium carbonate-water at 10, 30 and 50 degrees C[J]. CHINESE JOURNAL OF CHEMISTRY,2004,22(1):14-18.
APA Zhai, QG,Hu, MC,Liu, ZH,&Xia, SP.(2004).Study on the phase equilibrium of the ternary system ethanol-cesium carbonate-water at 10, 30 and 50 degrees C.CHINESE JOURNAL OF CHEMISTRY,22(1),14-18.
MLA Zhai, QG,et al."Study on the phase equilibrium of the ternary system ethanol-cesium carbonate-water at 10, 30 and 50 degrees C".CHINESE JOURNAL OF CHEMISTRY 22.1(2004):14-18.
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