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Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K and its compounds
Wang, H; Duan, JX; Ran, XQ; Gao, SY
2004-10-01
Source PublicationCHINESE JOURNAL OF CHEMISTRY
Volume22Issue:10Pages:1128-1132
SubtypeArticle
AbstractThe equilibrium solubility of one CsCl-YCl3-H2O ternary section Of CsCl-YCl3-9.5%HCl-H2O quaternary system at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase diagram was plotted. The crystallization of two new double salts Cs4YCl7.10H(2)O (4 : 1 type) and Cs3Y2Cl9.14H(2)O (3 : 2 type) was successful and they were obtained from the complicated system directly. Both were identified and characterized by X-ray, thermal analysis method of TG-DTG, DSC. The fluorescence experiments show that up-conversion phenomenon does not exist in compounds CS4YCl7.10H(2)O and Cs3Y2Cl9.14H(2)O.
KeywordSolubility Diagram Of Quaternary System Double Salts Cesium Chloride And Yttrium Chloride Compound Cs4ycl7 Center Dot 10h(2)o And Cs3y2cl9 Center Dot 14h(2)o
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordCHEMISTRY ; BROMIDES
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000224401100013
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6130
Collection青海盐湖研究所知识仓储
Affiliation1.NW Univ Xian, Dept Chem, Shaanxi Key Lab Physico Inorgan Chem, Xian 710069, Peoples R China
2.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
3.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xian 710043, Shaanxi, Peoples R China
Recommended Citation
GB/T 7714
Wang, H,Duan, JX,Ran, XQ,et al. Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K and its compounds[J]. CHINESE JOURNAL OF CHEMISTRY,2004,22(10):1128-1132.
APA Wang, H,Duan, JX,Ran, XQ,&Gao, SY.(2004).Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K and its compounds.CHINESE JOURNAL OF CHEMISTRY,22(10),1128-1132.
MLA Wang, H,et al."Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K and its compounds".CHINESE JOURNAL OF CHEMISTRY 22.10(2004):1128-1132.
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