Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K

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	Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K
	Jiang, YC ; Hu, MC ; Mu, PF ; Wang, JJ ; Zhuo, KL ; Xia, SP
	2004-09-01
发表期刊	JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号	49 期号:5 页码:1418-1421
摘要	Electromotive forces of cells without liquid junctions K-ISE \ CsCl(m(E)) \ ISE-Cl and K-ISE \ CsCl(m(E)), glucose(m(S)) \ ISE-Cl have been measured at 5 K intervals from T = 278.15 to 313.15 K, where m(E) = (0.001 to 0.1) mol kg(-1) and m(S) = (0.01 to 3.0) mol kg(-1). The activity coefficients of CsCl in glucose + water solutions can be obtained from these electromotive force data; in the meantime, the interaction parameters of the CsCl + glucose pair in water, g(EN), h(EN), s(EN), and c(p,EN), can be evaluated. We show that g(EN) > 0, h(EN) > 0, s(EN) > 0, and c(p,EN) < 0 at all four temperatures (except for h(EN) and s(EN) at T = 313.15 K), and the values of g(EN), s(EN), and c(p,EN) vary slightly with temperature, whereas the values of h(EN) is very sensitive to the temperatures used. These thermodynamic parameters were discussed in terms of a model of the structural interaction and electrostatic interaction and were analyzed by the group additivity principle.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/6132
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Shaanxi 710062, Peoples R China 2.Henan Normal Univ, Coll Chem & Environm Sci, Henan 453002, Peoples R China 3.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Shaanxi, Peoples R China
推荐引用方式 GB/T 7714	Jiang, YC,Hu, MC,Mu, PF,et al. Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2004,49(5):1418-1421.
APA	Jiang, YC,Hu, MC,Mu, PF,Wang, JJ,Zhuo, KL,&Xia, SP.(2004).Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,49(5),1418-1421.
MLA	Jiang, YC,et al."Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 49.5(2004):1418-1421.