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Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K
Jiang, YC; Hu, MC; Mu, PF; Wang, JJ; Zhuo, KL; Xia, SP
2004-09-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号49期号:5页码:1418-1421
文章类型Article
摘要Electromotive forces of cells without liquid junctions K-ISE \ CsCl(m(E)) \ ISE-Cl and K-ISE \ CsCl(m(E)), glucose(m(S)) \ ISE-Cl have been measured at 5 K intervals from T = 278.15 to 313.15 K, where m(E) = (0.001 to 0.1) mol kg(-1) and m(S) = (0.01 to 3.0) mol kg(-1). The activity coefficients of CsCl in glucose + water solutions can be obtained from these electromotive force data; in the meantime, the interaction parameters of the CsCl + glucose pair in water, g(EN), h(EN), s(EN), and c(p,EN), can be evaluated. We show that g(EN) > 0, h(EN) > 0, s(EN) > 0, and c(p,EN) < 0 at all four temperatures (except for h(EN) and s(EN) at T = 313.15 K), and the values of g(EN), s(EN), and c(p,EN) vary slightly with temperature, whereas the values of h(EN) is very sensitive to the temperatures used. These thermodynamic parameters were discussed in terms of a model of the structural interaction and electrostatic interaction and were analyzed by the group additivity principle.
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]AQUEOUS-SOLUTIONS ; MOLAR VOLUMES ; FREE-ENERGIES ; AMINO-ACIDS ; D-ARABINOSE ; D-GALACTOSE ; D-XYLOSE ; ENTHALPIES ; PARAMETERS ; ASSOCIATION
收录类别SCI
语种英语
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000223833100050
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6132
专题青海盐湖研究所知识仓储
作者单位1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Shaanxi 710062, Peoples R China
2.Henan Normal Univ, Coll Chem & Environm Sci, Henan 453002, Peoples R China
3.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Shaanxi, Peoples R China
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GB/T 7714
Jiang, YC,Hu, MC,Mu, PF,et al. Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2004,49(5):1418-1421.
APA Jiang, YC,Hu, MC,Mu, PF,Wang, JJ,Zhuo, KL,&Xia, SP.(2004).Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,49(5),1418-1421.
MLA Jiang, YC,et al."Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 49.5(2004):1418-1421.
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