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Cr-III and Cu-I complexes of 2,2 ',2 ''-(1H-imidazole-2,4,5-triyl)-tripyridine: In situ generation of imidazole ring from the coupling of picolinaldehyde and ammonium acetate
Qin, Yaru1; Chen, Yanmei1,2; Liu, Jinna1; Zhao, Jingjing1; Gao, Dandan2; Li, Yahong1; Liu, Wei1; Li, Wu2
2015-06-01
Source PublicationINORGANIC CHEMISTRY COMMUNICATIONS
Volume56Pages:58-61
SubtypeArticle
AbstractThe syntheses, characterizations and properties of two coordination complexes, [Cr-3(L)(3)Cl-6] (1) and [Cu-4(L)(2)Br-2](n) (2) (HL = 2,2',2 ''-(1H-imidazole-2,4,5-triyl)tripyridine) were reported. The HL ligand was unprecedentedly afforded by metal-mediated solverthermal in situ metal-ligand reaction among picolinaldehyde, ammonium acetate and metal ions. Compound I can be described as a bottom-opened vase-like complex with the three Cr-III ions showing a triangle conformation. For complex 2, the sandwich-like [Cu-4(L)(2)](2+) moieties are linked by bromide ions to generate a 1D chain framework Variable-temperature magnetic studies in the temperature range of 2.0-300 K for 1 reveal antiferromagnetic Cr-III center dot center dot center dot Cr-III interactions. The catalytic activity of 2 towards the reaction of 2-butanone and ethylene glycol was also investigated; it showed a very good catalytic property allowing for the easy and high yielding preparation of 2-ethyl-2-methyl-1,3-dioxolane under mild conditions. (C) 2015 Elsevier B.V. All rights reserved.
KeywordIn Situ Metal-ligand Reaction Magnetic Properties 2 Catalytic Activity 2 ' 2 ''-(1h-imidazole-2 4 5-triyl)Tripyridine
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordCHEMISTRY ; CRYSTAL ; LIGANDS
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000355045400012
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6136
Collection青海盐湖研究所知识仓储
Affiliation1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
Recommended Citation
GB/T 7714
Qin, Yaru,Chen, Yanmei,Liu, Jinna,et al. Cr-III and Cu-I complexes of 2,2 ',2 ''-(1H-imidazole-2,4,5-triyl)-tripyridine: In situ generation of imidazole ring from the coupling of picolinaldehyde and ammonium acetate[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2015,56:58-61.
APA Qin, Yaru.,Chen, Yanmei.,Liu, Jinna.,Zhao, Jingjing.,Gao, Dandan.,...&Li, Wu.(2015).Cr-III and Cu-I complexes of 2,2 ',2 ''-(1H-imidazole-2,4,5-triyl)-tripyridine: In situ generation of imidazole ring from the coupling of picolinaldehyde and ammonium acetate.INORGANIC CHEMISTRY COMMUNICATIONS,56,58-61.
MLA Qin, Yaru,et al."Cr-III and Cu-I complexes of 2,2 ',2 ''-(1H-imidazole-2,4,5-triyl)-tripyridine: In situ generation of imidazole ring from the coupling of picolinaldehyde and ammonium acetate".INORGANIC CHEMISTRY COMMUNICATIONS 56(2015):58-61.
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