Knowledge Management System Of Qinghai Institute of Salt Lakes,CAS
Hydrothermal Synthesis of Leaf-like LiFePO4/C Cathode Composites | |
Yun Qiang1,2; Zhou Yuan1![]() ![]() ![]() ![]() ![]() | |
2015-05-10 | |
发表期刊 | CHINESE JOURNAL OF INORGANIC CHEMISTRY
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卷号 | 31期号:5页码:880-887 |
关键词 | Materials Science Hydrothermal Synthesis Electrochemistry Lifepo4/c Micro-leaf Citric Acid |
摘要 | Highly-dispersed LiFePO4/C composite with micro-leaf structure was synthesized by a facile citric acid-assisted hydrothermal method in this study. Crystal structure and morphology of samples were investigated by XRD, FTIR, SEM, HR-TEM and selected area electron diffraction (SAED). The characterization results indicate that citric acid accelerates the formation of leaf-like LiFePO4/C composite. The as-prepared leaf-like LiFePO4/C composite with an enlarged (010) plane has high dispersibility. By comparing the electrochemical properties of the LiFePO4/C particles in our study, the LiFePO4/C micro-leaves exhibit larger discharge capacity and better rate performance, which deliver a discharge capacity of 158 mAh.g(-1) at 0.1C and 126 mAh.g(-1) at 5C. The enhanced performance perhaps is attributed to the reduced Li-ion diffusion paths along the [010] direction and larger Li-ion diffusion coefficient. |
语种 | 英语 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/6141 |
专题 | 青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 盐湖资源与化学实验室 |
作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Yun Qiang,Zhou Yuan,Hai Chun-Xi,et al. Hydrothermal Synthesis of Leaf-like LiFePO4/C Cathode Composites[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2015,31(5):880-887. |
APA | Yun Qiang.,Zhou Yuan.,Hai Chun-Xi.,Shen Yue.,Li Xiang.,...&Ding Xiu-Ping.(2015).Hydrothermal Synthesis of Leaf-like LiFePO4/C Cathode Composites.CHINESE JOURNAL OF INORGANIC CHEMISTRY,31(5),880-887. |
MLA | Yun Qiang,et al."Hydrothermal Synthesis of Leaf-like LiFePO4/C Cathode Composites".CHINESE JOURNAL OF INORGANIC CHEMISTRY 31.5(2015):880-887. |
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