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Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone
Zhao, Jing-Jing1; Pei, Hao1; Chen, Yan-Mei1,2; Lu, Ning1; Liu, Jin-Na1; Hu, Jin-Fa1; Liu, Wei1; Li, Wu2; Li, Yahong1
2015-06-01
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume641Issue:7Pages:1322-1328
SubtypeArticle
AbstractThe ligands 2-pyrazol-1-yl-1H-indole (HL1) and 2-1,2,4-triazol-1-yl-1H-indole (HL2) individually reacted with Ti(NMe2)(4) in tetrahydrofuran to form the corresponding complexes Ti(L1)(2)(NMe2)(2) (1) and Ti(L2)(2)(NMe2)(2) (2), respectively. The titanium complexes were fully characterized by NMR measurement and elemental analysis as well as the single-crystal X-ray diffraction of 1 and 2. Both 1 and 2 exhibit high activities towards intermolecular hydroamination of terminal alkynes with high selectivity, and they also efficiently promote the ring-opening polymerization of E-caprolactone.
KeywordHydroamination Titanium Ring-opening Polymerization E-caprolactone
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordINTRAMOLECULAR ALKENE HYDROAMINATION ; INTERMOLECULAR ALKYNE HYDROAMINATION ; N BOND FORMATION ; TITANIUM COMPLEXES ; C-N ; ALPHA,BETA-UNSATURATED IMINES ; ASYMMETRIC HYDROAMINATION ; AMIDATE COMPLEXES ; TERMINAL ALKYNES ; ZIRCONIUM
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000356722400023
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6146
Collection青海盐湖研究所知识仓储
盐湖资源综合利用工程技术中心
Affiliation1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Jing-Jing,Pei, Hao,Chen, Yan-Mei,et al. Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2015,641(7):1322-1328.
APA Zhao, Jing-Jing.,Pei, Hao.,Chen, Yan-Mei.,Lu, Ning.,Liu, Jin-Na.,...&Li, Yahong.(2015).Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,641(7),1322-1328.
MLA Zhao, Jing-Jing,et al."Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 641.7(2015):1322-1328.
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