Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone

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	Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone
	Zhao, Jing-Jing 1; Pei, Hao 1; Chen, Yan-Mei 1,2; Lu, Ning 1; Liu, Jin-Na 1; Hu, Jin-Fa 1; Liu, Wei 1; Li, Wu2 ; Li, Yahong 1
	2015-06-01
Source Publication	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume	641 Issue:7 Pages:1322-1328
Subtype	Article
Abstract	The ligands 2-pyrazol-1-yl-1H-indole (HL1) and 2-1,2,4-triazol-1-yl-1H-indole (HL2) individually reacted with Ti(NMe2)(4) in tetrahydrofuran to form the corresponding complexes Ti(L1)(2)(NMe2)(2) (1) and Ti(L2)(2)(NMe2)(2) (2), respectively. The titanium complexes were fully characterized by NMR measurement and elemental analysis as well as the single-crystal X-ray diffraction of 1 and 2. Both 1 and 2 exhibit high activities towards intermolecular hydroamination of terminal alkynes with high selectivity, and they also efficiently promote the ring-opening polymerization of E-caprolactone.
Keyword	Hydroamination Titanium Ring-opening Polymerization E-caprolactone
WOS Headings	Science & Technology ; Physical Sciences
WOS Keyword	INTRAMOLECULAR ALKENE HYDROAMINATION ; INTERMOLECULAR ALKYNE HYDROAMINATION ; N BOND FORMATION ; TITANIUM COMPLEXES ; C-N ; ALPHA,BETA-UNSATURATED IMINES ; ASYMMETRIC HYDROAMINATION ; AMIDATE COMPLEXES ; TERMINAL ALKYNES ; ZIRCONIUM
Indexed By	SCI
Language	英语
WOS Research Area	Chemistry
WOS Subject	Chemistry, Inorganic & Nuclear
WOS ID	WOS:000356722400023
Citation statistics
Document Type	期刊论文
Identifier	http://ir.isl.ac.cn/handle/363002/6146
Collection	青海盐湖研究所知识仓储盐湖资源综合利用工程技术中心
Affiliation	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
Recommended Citation GB/T 7714	Zhao, Jing-Jing,Pei, Hao,Chen, Yan-Mei,et al. Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2015,641(7):1322-1328.
APA	Zhao, Jing-Jing.,Pei, Hao.,Chen, Yan-Mei.,Lu, Ning.,Liu, Jin-Na.,...&Li, Yahong.(2015).Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,641(7),1322-1328.
MLA	Zhao, Jing-Jing,et al."Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 641.7(2015):1322-1328.

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