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A novel dual-salts of LiTFSI and LiODFB in LiFePO4-based batteries for suppressing aluminum corrosion and improving cycling stability
Li, Faqiang1,3; Gong, Yan1,2; Jia, Guofeng1,3,4; Wang, Qinglei1,2; Peng, Zhengjun1,3; Fan, Wei1,5; Bai, Bing1,5
2015-11-01
发表期刊JOURNAL OF POWER SOURCES
卷号295页码:47-54
文章类型Article
摘要The strong corrosion behavior at the Al current collector restricts the application range of lithium bis (trifluoromethanesulfonylimide) (LiTFSI), despite its high stability against water and thermal. SEM, LSV and Tafel curves proved that adding LiODFB into LiTFSI-based electrolytes could suppress aluminum corrosion caused by LiTFSI-based electrolytes. The cycling stability and rate capability of LiFePO4-based batteries using LiTFSI0.6-LiODFB0.4-based electrolytes is excellent as compared to LiFePO4-based batteries using LiPF6-based electrolytes. (C) 2015 Elsevier B.V. All rights reserved.
关键词Lithium-ion Batteries Dual-salts Electrolyte Aluminum Corrosion Cycling Stability
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]LITHIUM-ION BATTERIES ; PERFLUOROALKYLSULFONYL IMIDES ; SOLID-ELECTROLYTE ; LIPF6 ; LIBOB ; TEMPERATURE
收录类别SCI
语种英语
WOS研究方向Electrochemistry ; Energy & Fuels
WOS类目Electrochemistry ; Energy & Fuels
WOS记录号WOS:000359330500007
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6151
专题青海盐湖研究所知识仓储
盐湖资源与化学实验室
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Qinghai Low Temp Lithium Ion Battery Technol Engn, Xining 810008, Peoples R China
4.Cent S Univ, Changsha 410083, Peoples R China
5.Qinghai Green Grass Technol Co Ltd, Xining 810008, Peoples R China
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Li, Faqiang,Gong, Yan,Jia, Guofeng,et al. A novel dual-salts of LiTFSI and LiODFB in LiFePO4-based batteries for suppressing aluminum corrosion and improving cycling stability[J]. JOURNAL OF POWER SOURCES,2015,295:47-54.
APA Li, Faqiang.,Gong, Yan.,Jia, Guofeng.,Wang, Qinglei.,Peng, Zhengjun.,...&Bai, Bing.(2015).A novel dual-salts of LiTFSI and LiODFB in LiFePO4-based batteries for suppressing aluminum corrosion and improving cycling stability.JOURNAL OF POWER SOURCES,295,47-54.
MLA Li, Faqiang,et al."A novel dual-salts of LiTFSI and LiODFB in LiFePO4-based batteries for suppressing aluminum corrosion and improving cycling stability".JOURNAL OF POWER SOURCES 295(2015):47-54.
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