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A series of tetranuclear [Ln(4)] clusters with defect-dicubane cores including a Dy-4 single-molecule magnet
Zhang, Haifeng1; Zhang, Jin1; Li, Yahong1; Qin, Yaru1; Chen, Yanmei1,2; Liu, Wei1; Gao, Dandan2; Li, Wu2
2015
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
Volume68Issue:16Pages:2798-2809
SubtypeArticle
AbstractA series of tetranuclear lanthanide compounds, [Ln(4)((3)-OH)(2)L-4(NO3)(2)(DMF)(2)] (H2L=2-(2-hydroxy-3-methoxybenzylideneamino)phenol; Ln=Dy (1); Tb (2); Er (3); and Gd (4)), have been prepared under hydrothermal conditions. X-ray crystal structure analysis reveals that 1-4 are polymorphs. The cores of the structures can be described as co-planar defect-dicubane. The solid-state luminescent properties indicate that the Ln(III) ions have very deep influence on the luminescence of H2L. The magnetic properties for 1-4 were studied. The Dy-4 complex exhibits single-molecule magnet behavior.
KeywordSingle-molecule Magnet Defect-dicubane Luminescent Property Lanthanide Ions
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordCRYSTAL-STRUCTURE ; SLOW RELAXATION ; COMPLEXES ; BEHAVIOR ; FAMILY ; FIELD ; GD ; ION ; MAGNETIZATION ; LIGAND
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000359822900005
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6152
Collection青海盐湖研究所知识仓储
盐湖资源综合利用工程技术中心
Affiliation1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Haifeng,Zhang, Jin,Li, Yahong,et al. A series of tetranuclear [Ln(4)] clusters with defect-dicubane cores including a Dy-4 single-molecule magnet[J]. JOURNAL OF COORDINATION CHEMISTRY,2015,68(16):2798-2809.
APA Zhang, Haifeng.,Zhang, Jin.,Li, Yahong.,Qin, Yaru.,Chen, Yanmei.,...&Li, Wu.(2015).A series of tetranuclear [Ln(4)] clusters with defect-dicubane cores including a Dy-4 single-molecule magnet.JOURNAL OF COORDINATION CHEMISTRY,68(16),2798-2809.
MLA Zhang, Haifeng,et al."A series of tetranuclear [Ln(4)] clusters with defect-dicubane cores including a Dy-4 single-molecule magnet".JOURNAL OF COORDINATION CHEMISTRY 68.16(2015):2798-2809.
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