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Synthesis and Structural Characterizations of a New Lithium Salt for Lithium-ion Batteries
Jia Guo-Feng1,2; Li Fa-Qiang1; Peng Zheng-Jun1; Zhu Zeng-Hu1; Gong Yan1,3; Wang Qing-Lei1,3
2015-08-12
发表期刊CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
卷号34期号:8页码:1197-1202
文章类型Article
摘要A novel crystal [(CH3O)(2)CO](3)Li-2[C2BF2O4](2) was synthesized and fully characterized by FT-IR and single-crystal X-ray diffraction analysis. It crystallizes in monoclinic system, P2(1)/n space group, with a = 8.1749(2), b = 10.7449(2), c = 12.8665(3) angstrom, beta = 94.654(2)degrees, V = 1126.45(4) angstrom(3), Z = 2, D-c = 1.644 g/cm, F(000) = 568, mu = 1.498 mm(-1), M-r = 557.77 g/mol, the final R = 0.0334 and wR = 0.0903. The structure analysis revealed that each Li atom is three-coordinated and adopts 1.5 O atoms of two different dimethyl carbonates and one O atom of C2BF2O4-. Thermal stability and infrared spectra analysis were studied and discussed.
关键词Lithium Salt Solid-organic Solvent Synthesis Crystallization Crystal Structure Lithium-ion Battery
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]ELECTROCHEMICAL PROPERTIES ; ELECTROLYTES ; LIBOB
收录类别SCI
语种英语
WOS研究方向Chemistry ; Crystallography
WOS类目Chemistry, Inorganic & Nuclear ; Crystallography
WOS记录号WOS:000361034600006
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6154
专题青海盐湖研究所知识仓储
盐湖资源与化学实验室
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
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Jia Guo-Feng,Li Fa-Qiang,Peng Zheng-Jun,et al. Synthesis and Structural Characterizations of a New Lithium Salt for Lithium-ion Batteries[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2015,34(8):1197-1202.
APA Jia Guo-Feng,Li Fa-Qiang,Peng Zheng-Jun,Zhu Zeng-Hu,Gong Yan,&Wang Qing-Lei.(2015).Synthesis and Structural Characterizations of a New Lithium Salt for Lithium-ion Batteries.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,34(8),1197-1202.
MLA Jia Guo-Feng,et al."Synthesis and Structural Characterizations of a New Lithium Salt for Lithium-ion Batteries".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 34.8(2015):1197-1202.
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