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Solubilities, Densities, and Refractive Indices in the Salt-Water Ternary System (LiCI + LiBO2 + H2O) at T=288.15 K and 298.15 K and p=0.1 MPa
Gao, Daolin1,2; Guo, Yafei1,2,3; Yu, Xiaoping2; Wang, Shiqiang2; Deng, Tianlong2
2015-09-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号60期号:9页码:2594-2599
文章类型Article
摘要Solubilities, densities, and refractive indices for the salt-water ternary system (LiCl + LiBO2 + H2O) at T = 288.15 K and 298.15 K and p = 0.1 MPa were determined using the isothermal dissolution equilibrium method. According to the experimental data at two temperatures, the phase diagrams and the diagrams of densities and refractive indices versus lithium chloride composition in the solution were plotted, respectively. In the phase diagrams at 288.15 K and 298.15 K, in all there are three crystallizing regions corresponding to lithium metaborate octahydrate (LiBO(2 center dot)8H(2)O, Lb8), lithium metaborate dihydrate (LiBO2 center dot 2H(2)O, Lb2), and lithium chloride monohydrate (LiCl.H2O, Lc1), three univariant curves and two invariant points corresponding to (Lb8 + Lb2) and (Lb2 + Lc1). It was found that there are two kinds of hydrates for lithium metaborates (Lb8 and Lb2) formed at both termperatures, and the hydrate for lithium metaborate belongs to hydrate type II. Neither double salts nor solid solutions were found. A comparison of the phase diagrams at two temperatures shows that the areas of the crystalline regions of Lb8 and Lc1 are decreased and that of Lb2 is increased with increasing temperature. The density and refractive index in the ternary system at two temperatures change regularly with the increasing LiCl mass fraction in the solution to reach the maximum values in the ternary-invariant-point. The correlation equations of density and refractive index were used, and the calculated results agree well with the experimental data.
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]METASTABLE PHASE-EQUILIBRIUM ; QUATERNARY SYSTEM ; BORATE IONS ; 308.15 K ; LITHIUM ; POTASSIUM ; CHLORIDE ; SODIUM ; EXTRACTION ; (NA2SO4
收录类别SCI
语种英语
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000361253500008
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6155
专题青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Tianjin Univ Sci & Technol, Coll Chem Engn & Mat Sci, Tianjin Key Lab Marine Resources & Chem, Tianjin 300457, Peoples R China
3.NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Peoples R China
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Gao, Daolin,Guo, Yafei,Yu, Xiaoping,et al. Solubilities, Densities, and Refractive Indices in the Salt-Water Ternary System (LiCI + LiBO2 + H2O) at T=288.15 K and 298.15 K and p=0.1 MPa[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2015,60(9):2594-2599.
APA Gao, Daolin,Guo, Yafei,Yu, Xiaoping,Wang, Shiqiang,&Deng, Tianlong.(2015).Solubilities, Densities, and Refractive Indices in the Salt-Water Ternary System (LiCI + LiBO2 + H2O) at T=288.15 K and 298.15 K and p=0.1 MPa.JOURNAL OF CHEMICAL AND ENGINEERING DATA,60(9),2594-2599.
MLA Gao, Daolin,et al."Solubilities, Densities, and Refractive Indices in the Salt-Water Ternary System (LiCI + LiBO2 + H2O) at T=288.15 K and 298.15 K and p=0.1 MPa".JOURNAL OF CHEMICAL AND ENGINEERING DATA 60.9(2015):2594-2599.
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