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Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach
Wang, Ya-bin1,2; Huang, Yu-dong1; Qi, Yu-tai1
2016-11-01
发表期刊TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
卷号26期号:11页码:2947-2959
文章类型Article
摘要A multifunctional polymeric nanofilm of triazinedithiolsilane monosodium salt, which can resist corrosion and activate copper surface concurrently, was prepared by galvanostatic technique and the following hydrolysis-condensation approach. Electrochemical tests were carried out to evaluate the resistant ability of nanofilm. The changes of functional groups atop the nanofilms were monitored with Fourier transform infrared spectroscopy (FT-IR) and contact angles (CA) simultaneously. The chemical composition and the morphology of the polymeric nanofilm were investigated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM), respectively. The results reveal that the preferentially developed disulfide units protect the copper during the whole preparation process, and the subsequently hydrolyzed nanofilms without/with heating shape into new interface phases bearing the multifunctionality. This multifunctional interface (the polymeric nanofilm on copper surface) opens up the possibilities for other OH-containing reagents to be anchored onto copper surface in demanding researches or industrial applications.
关键词Copper Triazinedithiolsilane Galvanostatic Technique Multifunctional Polymeric Nanofilm Functionalized Interface
WOS标题词Science & Technology ; Technology
关键词[WOS]AZ31 MAGNESIUM ALLOY ; WT.PERCENT NACL ; FILM ; INHIBITION ; MONOLAYERS ; IRON ; SPECTROSCOPY ; RESISTANCE ; PROTECTION ; COATINGS
收录类别SCI
语种英语
WOS研究方向Metallurgy & Metallurgical Engineering
WOS类目Metallurgy & Metallurgical Engineering
WOS记录号WOS:000389519700019
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6178
专题青海盐湖研究所知识仓储
作者单位1.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
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GB/T 7714
Wang, Ya-bin,Huang, Yu-dong,Qi, Yu-tai. Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2016,26(11):2947-2959.
APA Wang, Ya-bin,Huang, Yu-dong,&Qi, Yu-tai.(2016).Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,26(11),2947-2959.
MLA Wang, Ya-bin,et al."Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 26.11(2016):2947-2959.
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