Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach

ISL OpenIR > 青海盐湖研究所知识仓储

	Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach
	Wang, Ya-bin 1,2; Huang, Yu-dong 1; Qi, Yu-tai 1
	2016-11-01
发表期刊	TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
卷号	26 期号:11 页码:2947-2959
关键词	Copper Triazinedithiolsilane Galvanostatic Technique Multifunctional Polymeric Nanofilm Functionalized Interface
摘要	A multifunctional polymeric nanofilm of triazinedithiolsilane monosodium salt, which can resist corrosion and activate copper surface concurrently, was prepared by galvanostatic technique and the following hydrolysis-condensation approach. Electrochemical tests were carried out to evaluate the resistant ability of nanofilm. The changes of functional groups atop the nanofilms were monitored with Fourier transform infrared spectroscopy (FT-IR) and contact angles (CA) simultaneously. The chemical composition and the morphology of the polymeric nanofilm were investigated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM), respectively. The results reveal that the preferentially developed disulfide units protect the copper during the whole preparation process, and the subsequently hydrolyzed nanofilms without/with heating shape into new interface phases bearing the multifunctionality. This multifunctional interface (the polymeric nanofilm on copper surface) opens up the possibilities for other OH-containing reagents to be anchored onto copper surface in demanding researches or industrial applications.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/6178
专题	青海盐湖研究所知识仓储
作者单位	1.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式 GB/T 7714	Wang, Ya-bin,Huang, Yu-dong,Qi, Yu-tai. Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2016,26(11):2947-2959.
APA	Wang, Ya-bin,Huang, Yu-dong,&Qi, Yu-tai.(2016).Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,26(11),2947-2959.
MLA	Wang, Ya-bin,et al."Fabricating multifunctional polymeric nanofilm capable of resisting corrosion and activating copper surface by electrochemical and hydrolysis-condensation approach".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 26.11(2016):2947-2959.