ISL OpenIR  > 青海盐湖研究所知识仓储
Syntheses, structures, and magnetic properties of a cubane-like {Co4O4} cluster and a dinuclear Cull compound constructed from a tridentate Schiff base ligand
Sun, Hao1; Zhang, Jin1; Cai, Yanping1; Liu, Wei1; Zhang, Xiangfei2; Dong, Yaping2; Li, Yahong1
2017-03-29
发表期刊POLYHEDRON
卷号125页码:135-140
文章类型Article
摘要The employment of a tridentate Schiff base ligand, 1-(((2-hydroxy-2,3-dihydro-1H-inden-1-yl)imino) methyl)naphthalen-2-ol (H2L) in the coordination chemistry of cobalt(II) acetate and copper(II) acetate is reported. One cubane-like cluster of formula [Co4L4].CH3OH (1.CH3OH) and one alkoxo-bridged dinuclear copper compound of composition [Cu2L2] (2) were achieved by the reactions of metal acetates with H2L under solvothermal conditions. The structures of 1.CH3OH and 2 have been established by single crystal X-ray diffraction studies. Complex 1"CH3OH has a cubane-like (Co4O4) core with divalent metal atoms and alkoxo atoms (originated from the L2- ligands) occupying alternating vertices. The magnetic properties of 1"CH3OH and 2 have been investigated. The variable-temperature de magnetic susceptibility studies indicate ferromagnetic Co-II...Co-II exchange interactions for 1.CH3OH and antiferromagnetic Cu-II...Cu-II couplings for 2. The ac magnetic susceptibility investigation reveals that complex 1.CH3OH shows the slow magnetic relaxation (SMM) behavior. (C) 2016 Elsevier Ltd. All rights reserved.
关键词Crystal Structures Schiff Base Cubane Single Molecule Magnets Clusters
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]WATER OXIDATION ; COBALT OXIDE ; CO-II ; COMPLEXES ; LUMINESCENT ; CHEMISTRY ; CATALYSTS
收录类别SCI
语种英语
WOS研究方向Chemistry ; Crystallography
WOS类目Chemistry, Inorganic & Nuclear ; Crystallography
WOS记录号WOS:000397834400020
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6198
专题青海盐湖研究所知识仓储
盐湖资源综合利用工程技术中心
作者单位1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Sun, Hao,Zhang, Jin,Cai, Yanping,et al. Syntheses, structures, and magnetic properties of a cubane-like {Co4O4} cluster and a dinuclear Cull compound constructed from a tridentate Schiff base ligand[J]. POLYHEDRON,2017,125:135-140.
APA Sun, Hao.,Zhang, Jin.,Cai, Yanping.,Liu, Wei.,Zhang, Xiangfei.,...&Li, Yahong.(2017).Syntheses, structures, and magnetic properties of a cubane-like {Co4O4} cluster and a dinuclear Cull compound constructed from a tridentate Schiff base ligand.POLYHEDRON,125,135-140.
MLA Sun, Hao,et al."Syntheses, structures, and magnetic properties of a cubane-like {Co4O4} cluster and a dinuclear Cull compound constructed from a tridentate Schiff base ligand".POLYHEDRON 125(2017):135-140.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Sun, Hao]的文章
[Zhang, Jin]的文章
[Cai, Yanping]的文章
百度学术
百度学术中相似的文章
[Sun, Hao]的文章
[Zhang, Jin]的文章
[Cai, Yanping]的文章
必应学术
必应学术中相似的文章
[Sun, Hao]的文章
[Zhang, Jin]的文章
[Cai, Yanping]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。