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Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites
Dang, Li1,2,3; Nai, Xue-ying2; Liu, Xin2; Zhu, Dong-hai2; Dong, Ya-ping2; Li, Wu1,2
2017-09-01
发表期刊CHINESE JOURNAL OF POLYMER SCIENCE
卷号35期号:9页码:1143-1155
文章类型Article
摘要The effects of maleic anhydride-grafted polypropylene (PP-g-MAH) and maleic anhydride-grafted polyolefin elastomer (POE-g-MAH) on interfacial adhesion properties of the polypropylene/magnesium oxysulfate whiskers (PP/MOSw) composites were investigated via mechanical, thermal, ATR-FTIR and rheological tests. Although significant increases in yield strength and Young's modulus were observed in PP-g-MAH treated composites, a sharp decline in these properties was observed in POE-g-MAH treated composites. ATR-FTIR results indicated that esterification occurred between the hydroxyl groups of MOSw and the carbonyls of anhydrides of both compatibilizers but POE-g-MAH was still incompatible with the PP matrix, as verified by the presence of shoulder peaks in DTG curves and numerous voids in SEM micrographs. On the other hand, PP-g-MAH was highly compatible with the PP matrix, as evidenced by the peaks in DTG curves and vague interfaces with wrapped melts on the surface of MOSw. Rheological behaviors also confirmed that introducing PP-g-MAH resulted in a transition from liquid-like to solid-like, which was attributed to the stronger interfacial adhesion between MOSw and the PP matrix. POE-g-MAH treated composites, in contrast to PP-g-MAH, maintained liquidlike rheological behaviors as typical molten polymers. There is likely a MOSw network formed in the PP/15PP-gMAH/15MOSw composite as suggested by the significant deviation of G' versus G''. plots and the two crossover frequencies observed in plots of tand versus frequency.
关键词Compatibility Interfacial Adhesion Mechanical Properties Rheological Behaviors
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]ANHYDRIDE-GRAFTED POLYPROPYLENE ; SULFATE HYDRATE WHISKER ; MECHANICAL-PROPERTIES ; MALEIC-ANHYDRIDE ; HYDROTHERMAL FORMATION ; THERMAL-STABILITY ; FIRE PERFORMANCE ; COUPLING AGENTS ; NANOCOMPOSITES ; CELLULOSE
收录类别SCI
语种英语
WOS研究方向Polymer Science
WOS类目Polymer Science
WOS记录号WOS:000405961000010
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6238
专题青海盐湖研究所知识仓储
盐湖资源综合利用工程技术中心
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources Chem, Xining 810008, Qinghai, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Qinghai, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Dang, Li,Nai, Xue-ying,Liu, Xin,et al. Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2017,35(9):1143-1155.
APA Dang, Li,Nai, Xue-ying,Liu, Xin,Zhu, Dong-hai,Dong, Ya-ping,&Li, Wu.(2017).Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites.CHINESE JOURNAL OF POLYMER SCIENCE,35(9),1143-1155.
MLA Dang, Li,et al."Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites".CHINESE JOURNAL OF POLYMER SCIENCE 35.9(2017):1143-1155.
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