Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites

ISL OpenIR > 青海盐湖研究所知识仓储

	Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites
	Dang, Li 1,2,3; Nai, Xue-ying2 ; Liu, Xin2 ; Zhu, Dong-hai 2; Dong, Ya-ping2 ; Li, Wu1,2
	2017-09-01
发表期刊	CHINESE JOURNAL OF POLYMER SCIENCE
卷号	35 期号:9 页码:1143-1155
关键词	Compatibility Interfacial Adhesion Mechanical Properties Rheological Behaviors
摘要	The effects of maleic anhydride-grafted polypropylene (PP-g-MAH) and maleic anhydride-grafted polyolefin elastomer (POE-g-MAH) on interfacial adhesion properties of the polypropylene/magnesium oxysulfate whiskers (PP/MOSw) composites were investigated via mechanical, thermal, ATR-FTIR and rheological tests. Although significant increases in yield strength and Young's modulus were observed in PP-g-MAH treated composites, a sharp decline in these properties was observed in POE-g-MAH treated composites. ATR-FTIR results indicated that esterification occurred between the hydroxyl groups of MOSw and the carbonyls of anhydrides of both compatibilizers but POE-g-MAH was still incompatible with the PP matrix, as verified by the presence of shoulder peaks in DTG curves and numerous voids in SEM micrographs. On the other hand, PP-g-MAH was highly compatible with the PP matrix, as evidenced by the peaks in DTG curves and vague interfaces with wrapped melts on the surface of MOSw. Rheological behaviors also confirmed that introducing PP-g-MAH resulted in a transition from liquid-like to solid-like, which was attributed to the stronger interfacial adhesion between MOSw and the PP matrix. POE-g-MAH treated composites, in contrast to PP-g-MAH, maintained liquidlike rheological behaviors as typical molten polymers. There is likely a MOSw network formed in the PP/15PP-gMAH/15MOSw composite as suggested by the significant deviation of G' versus G''. plots and the two crossover frequencies observed in plots of tand versus frequency.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/6238
专题	青海盐湖研究所知识仓储盐湖资源综合利用工程技术中心
作者单位	1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources Chem, Xining 810008, Qinghai, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Qinghai, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Dang, Li,Nai, Xue-ying,Liu, Xin,et al. Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2017,35(9):1143-1155.
APA	Dang, Li,Nai, Xue-ying,Liu, Xin,Zhu, Dong-hai,Dong, Ya-ping,&Li, Wu.(2017).Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites.CHINESE JOURNAL OF POLYMER SCIENCE,35(9),1143-1155.
MLA	Dang, Li,et al."Effects of Different Compatibilizing Agents on the Interfacial Adhesion Properties of Polypropylene/Magnesium Oxysulfate Whisker Composites".CHINESE JOURNAL OF POLYMER SCIENCE 35.9(2017):1143-1155.