ISL OpenIR  > 青海盐湖研究所知识仓储
Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural
Liu, Yong1; Li, Zili1; You, Yaohui1; Zheng, Xiaogang1; Wen, Jing2
2017
发表期刊RSC ADVANCES
卷号7期号:81页码:51281-51289
文章类型Article
摘要FePO4 catalysts with branch-like, flower-like, and spherical morphologies were synthesized for the conversion of methyl cellulose to 5-hydroxymethylfurfural (5-HMF) via a hydrothermal route. The molar ratio of Fe3+ and H2PO4- ions in the reaction system played a crucial role in the morphology of FePO4. Compared with flower-like, spherical and amorphous FePO4, branch-like FePO4 presented a better catalytic performance in the cellulose conversion and 5-HMF yield. The branch-like FePO4 retained a branch structure after recycling five times in the bi-phasic reaction process. The insolubility of low temperature and partial dissolution of elevated temperature were responsible for the excellent catalytic activity of the FePO4 phase-change catalyst. The combined effect of H+ ions and iron species generated from the hydrolysis of FePO4 can be favorable for the enhanced yield of 5-HMF.
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]BRONSTED ACID CATALYSTS ; IONIC-LIQUID-MIXTURES ; EFFICIENT CONVERSION ; FRUCTOSE CONVERSION ; LEVULINIC ACID ; GLUCOSE DEHYDRATION ; DIMETHYL-SULFOXIDE ; AMORPHOUS FEPO4 ; LEWIS ; OXIDE
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000414780700024
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6274
专题青海盐湖研究所知识仓储
盐湖资源与化学实验室
作者单位1.Neijiang Normal Univ, Coll Chem & Chem Engn, Neijiang 641100, Sichuan, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Qinghai, Peoples R China
推荐引用方式
GB/T 7714
Liu, Yong,Li, Zili,You, Yaohui,et al. Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural[J]. RSC ADVANCES,2017,7(81):51281-51289.
APA Liu, Yong,Li, Zili,You, Yaohui,Zheng, Xiaogang,&Wen, Jing.(2017).Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural.RSC ADVANCES,7(81),51281-51289.
MLA Liu, Yong,et al."Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural".RSC ADVANCES 7.81(2017):51281-51289.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Liu, Yong]的文章
[Li, Zili]的文章
[You, Yaohui]的文章
百度学术
百度学术中相似的文章
[Liu, Yong]的文章
[Li, Zili]的文章
[You, Yaohui]的文章
必应学术
必应学术中相似的文章
[Liu, Yong]的文章
[Li, Zili]的文章
[You, Yaohui]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。