Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural

doi:10.1039/c7ra09186a

ISL OpenIR > 青海盐湖研究所知识仓储

	Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural
	Liu, Yong; Li, Zili; You, Yaohui; Zheng, Xiaogang; Wen, Jing
第一作者	Liu, Yong
	2017
发表期刊	RSC ADVANCES
ISSN	2046-2069
卷号	7 期号:81 页码:51281-51289
摘要	FePO4 catalysts with branch-like, flower-like, and spherical morphologies were synthesized for the conversion of methyl cellulose to 5-hydroxymethylfurfural (5-HMF) via a hydrothermal route. The molar ratio of Fe3+ and H2PO4- ions in the reaction system played a crucial role in the morphology of FePO4. Compared with flower-like, spherical and amorphous FePO4, branch-like FePO4 presented a better catalytic performance in the cellulose conversion and 5-HMF yield. The branch-like FePO4 retained a branch structure after recycling five times in the bi-phasic reaction process. The insolubility of low temperature and partial dissolution of elevated temperature were responsible for the excellent catalytic activity of the FePO4 phase-change catalyst. The combined effect of H+ ions and iron species generated from the hydrolysis of FePO4 can be favorable for the enhanced yield of 5-HMF.
DOI	10.1039/c7ra09186a
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/6274
专题	青海盐湖研究所知识仓储盐湖资源与化学实验室
推荐引用方式 GB/T 7714	Liu, Yong,Li, Zili,You, Yaohui,et al. Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural[J]. RSC ADVANCES,2017,7(81):51281-51289.
APA	Liu, Yong,Li, Zili,You, Yaohui,Zheng, Xiaogang,&Wen, Jing.(2017).Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural.RSC ADVANCES,7(81),51281-51289.
MLA	Liu, Yong,et al."Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural".RSC ADVANCES 7.81(2017):51281-51289.

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Synthesis of differe（4391KB）	期刊论文	出版稿	开放获取	CC BY-NC-SA	浏览请求全文