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Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural
Liu, Yong1; Li, Zili1; You, Yaohui1; Zheng, Xiaogang1; Wen, Jing2
2017
Source PublicationRSC ADVANCES
Volume7Issue:81Pages:51281-51289
SubtypeArticle
AbstractFePO4 catalysts with branch-like, flower-like, and spherical morphologies were synthesized for the conversion of methyl cellulose to 5-hydroxymethylfurfural (5-HMF) via a hydrothermal route. The molar ratio of Fe3+ and H2PO4- ions in the reaction system played a crucial role in the morphology of FePO4. Compared with flower-like, spherical and amorphous FePO4, branch-like FePO4 presented a better catalytic performance in the cellulose conversion and 5-HMF yield. The branch-like FePO4 retained a branch structure after recycling five times in the bi-phasic reaction process. The insolubility of low temperature and partial dissolution of elevated temperature were responsible for the excellent catalytic activity of the FePO4 phase-change catalyst. The combined effect of H+ ions and iron species generated from the hydrolysis of FePO4 can be favorable for the enhanced yield of 5-HMF.
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordBRONSTED ACID CATALYSTS ; IONIC-LIQUID-MIXTURES ; EFFICIENT CONVERSION ; FRUCTOSE CONVERSION ; LEVULINIC ACID ; GLUCOSE DEHYDRATION ; DIMETHYL-SULFOXIDE ; AMORPHOUS FEPO4 ; LEWIS ; OXIDE
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000414780700024
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6274
Collection青海盐湖研究所知识仓储
盐湖资源与化学实验室
Affiliation1.Neijiang Normal Univ, Coll Chem & Chem Engn, Neijiang 641100, Sichuan, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Qinghai, Peoples R China
Recommended Citation
GB/T 7714
Liu, Yong,Li, Zili,You, Yaohui,et al. Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural[J]. RSC ADVANCES,2017,7(81):51281-51289.
APA Liu, Yong,Li, Zili,You, Yaohui,Zheng, Xiaogang,&Wen, Jing.(2017).Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural.RSC ADVANCES,7(81),51281-51289.
MLA Liu, Yong,et al."Synthesis of different structured FePO4 for the enhanced conversion of methyl cellulose to 5-hydroxymethylfurfural".RSC ADVANCES 7.81(2017):51281-51289.
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