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Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System
Jiang, Juan1; Yin, Xia1; Li, Dongdong2; Tan, Yuqi1; Zeng, Dewen3
2016-03-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号61期号:3页码:1125-1130
文章类型Article
摘要Solubility isotherms of the ternary Ca(NO3)(2)-LiNO3-H2O system were elab-orately determined at T = (273.15, 298.15, and 323.15 K) by an isothermal equilibrium method, and the results showed that there are two stable solubility branches for the solid phases Ca(NO3)(2)center dot 4H(2)O and LiNO3 center dot 3H(2)O at 273.15 K, and four stable solubility isotherms for the solid phases Ca(NO3)(2)center dot 4H(2)O, Ca(NO3)(2)center dot 3H(2)O, LiNO3 center dot 3H(2)O, and LiNO3 at 298.15 K, and solubility data corresponding to solid phases Ca(NO3)(2)center dot 3H(2)O, Ca(NO3)(2)center dot 2H(2)O, and LiNO3 at 323.15 K. The experimental data were correlated by a modified Brunauer-Emmett-Teller (BET) model, to obtain the complete phase diagram of the ternary system over the temperature range from 273 to 373 K. On the basis of the simulated polytherms, an eutectic point Ca(NO3)(2)center dot 4H(2)O + LiNO3 center dot 3H(2)O was recognized, and the melting temperature and fusion heat are 290.5 K and 139.8 J-g(-1), respectively, measured by differential scanning calorimetry.
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]CONCENTRATED-SOLUTIONS ; WATER ACTIVITIES ; ELECTROLYTE ; PREDICTION ; (LICL
收录类别SCI
语种英语
WOS研究方向Thermodynamics ; Chemistry ; Engineering
WOS类目Thermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000372043600012
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6306
专题青海盐湖研究所知识仓储
作者单位1.Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Peoples R China
3.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
推荐引用方式
GB/T 7714
Jiang, Juan,Yin, Xia,Li, Dongdong,et al. Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2016,61(3):1125-1130.
APA Jiang, Juan,Yin, Xia,Li, Dongdong,Tan, Yuqi,&Zeng, Dewen.(2016).Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System.JOURNAL OF CHEMICAL AND ENGINEERING DATA,61(3),1125-1130.
MLA Jiang, Juan,et al."Solubility Phase Diagram of the Ca(NO3)(2)-LiNO3-H2O System".JOURNAL OF CHEMICAL AND ENGINEERING DATA 61.3(2016):1125-1130.
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