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beta-Furan-Fused bis(Difluoroboron)-1,2-bis((1H-pyrrol-2-yl)methylene)hydrazine Fluorescent Dyes in the Visible Deep-Red Region
Zhou, Lin1; Xu, Defang2; Gao, Huaizhi1; Zhang, Chao1; Ni, Fangfang1; Zhao, Wenqi1; Cheng, Dandan1; Liu, Xingliang1; Han, Aixia1
2016-09-02
发表期刊JOURNAL OF ORGANIC CHEMISTRY
卷号81期号:17页码:7439-7447
文章类型Article
摘要Novel beta-furan-fused bis(difluoroboron)-1,2-bis-((1H-p-yrrol-2-yl)methylene)hydrazine (BOPHY) fluorescent dyes (F-BOPHY1-3) were prepared through an efficient process, and their structures were confirmed by H-1 NMR spectroscopy, C-13 NMR spectroscopy, MALDI-TOF HRMS, and element analysis. Their optical properties were then characterized by UV-vis absorption and photoluminescence (PL) spectroscopy. The UV-vis absorption and PL spectra of the dyes shifted to longer wavelengths relative to those of BOPHY because of the fusion of their furan rings, which extended pi-conjugation of the molecules. All of the dyes exhibited large extinction coefficients (109700-12300 M-1 cm(-1)), deep-red fluorescence emission (646-667 nm), moderate fluorescence quantum yields (0.30-0.45), as well as high chemical stability and photostability in solution. These advantageous properties show that these compounds are important to the design of efficient long-wavelength fluorescent dyes and are suitable for various applications in biotechnology and materials science.
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]AGGREGATION-INDUCED EMISSION ; BORON DIFLUORIDE DYES ; NEAR-INFRARED DYES ; LIGHT-EMITTING-DIODES ; HIGHLY FLUORESCENT ; BODIPY DYES ; BORATE COMPLEXES ; PHOTODYNAMIC THERAPY ; OPTICAL-PROPERTIES ; FACILE SYNTHESIS
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Organic
WOS记录号WOS:000382713800014
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6346
专题青海盐湖研究所知识仓储
作者单位1.Qinghai Univ, Chem Engn Coll, Xining 810016, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Peoples R China
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GB/T 7714
Zhou, Lin,Xu, Defang,Gao, Huaizhi,et al. beta-Furan-Fused bis(Difluoroboron)-1,2-bis((1H-pyrrol-2-yl)methylene)hydrazine Fluorescent Dyes in the Visible Deep-Red Region[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(17):7439-7447.
APA Zhou, Lin.,Xu, Defang.,Gao, Huaizhi.,Zhang, Chao.,Ni, Fangfang.,...&Han, Aixia.(2016).beta-Furan-Fused bis(Difluoroboron)-1,2-bis((1H-pyrrol-2-yl)methylene)hydrazine Fluorescent Dyes in the Visible Deep-Red Region.JOURNAL OF ORGANIC CHEMISTRY,81(17),7439-7447.
MLA Zhou, Lin,et al."beta-Furan-Fused bis(Difluoroboron)-1,2-bis((1H-pyrrol-2-yl)methylene)hydrazine Fluorescent Dyes in the Visible Deep-Red Region".JOURNAL OF ORGANIC CHEMISTRY 81.17(2016):7439-7447.
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