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A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property
Lin, Feng1,2; Dong, Yaping1; Peng, Jiaoyu1; Wang, Liping1,2; Li, Wu1; Yang, Bo1
2016-10-01
Source PublicationPHASE TRANSITIONS
Volume89Issue:10Pages:996-1005
SubtypeArticle
AbstractA new acentric mixed metal borate of composition K2Ba[B4O5(OH)(4)](2)10H(2)O, has been successfully obtained by slow evaporation solution method. The compound crystallizes in the Orthorhombic space group Pna21 (No.33) with a = 16.8668(7) angstrom, b = 13.0903(5) angstrom, c = 11.5529(5) angstrom and Z = 4. [B4O5(OH)(4)](2-) clusters serve as fundamental building unit linking with BaO8, K1O(6), K2O(7) by common O atoms to form three-dimensional layer structure. The second harmonic generation measurements in the powder samples reveal that the compound exhibits approximately 0.5times that of KH2PO4 (KDP) and phase matching.
KeywordSlow Evaporation Method Nonlinear Optical Hydrate Borate
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordCRYSTAL-STRUCTURE ; BARIUM BORATE
Indexed BySCI
Language英语
WOS Research AreaCrystallography ; Physics
WOS SubjectCrystallography ; Physics, Condensed Matter
WOS IDWOS:000387145700003
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6366
Collection青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
盐湖资源综合利用工程技术中心
Affiliation1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Salt Lake Comprehens Utilizat Resources Engn Tech, Xining, Peoples R China
2.Univ Chinese Acad Sci, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Lin, Feng,Dong, Yaping,Peng, Jiaoyu,et al. A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property[J]. PHASE TRANSITIONS,2016,89(10):996-1005.
APA Lin, Feng,Dong, Yaping,Peng, Jiaoyu,Wang, Liping,Li, Wu,&Yang, Bo.(2016).A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property.PHASE TRANSITIONS,89(10),996-1005.
MLA Lin, Feng,et al."A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property".PHASE TRANSITIONS 89.10(2016):996-1005.
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