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A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property
Lin, Feng1,2; Dong, Yaping1; Peng, Jiaoyu1; Wang, Liping1,2; Li, Wu1; Yang, Bo1
2016-10-01
发表期刊PHASE TRANSITIONS
卷号89期号:10页码:996-1005
文章类型Article
摘要A new acentric mixed metal borate of composition K2Ba[B4O5(OH)(4)](2)10H(2)O, has been successfully obtained by slow evaporation solution method. The compound crystallizes in the Orthorhombic space group Pna21 (No.33) with a = 16.8668(7) angstrom, b = 13.0903(5) angstrom, c = 11.5529(5) angstrom and Z = 4. [B4O5(OH)(4)](2-) clusters serve as fundamental building unit linking with BaO8, K1O(6), K2O(7) by common O atoms to form three-dimensional layer structure. The second harmonic generation measurements in the powder samples reveal that the compound exhibits approximately 0.5times that of KH2PO4 (KDP) and phase matching.
关键词Slow Evaporation Method Nonlinear Optical Hydrate Borate
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]CRYSTAL-STRUCTURE ; BARIUM BORATE
收录类别SCI
语种英语
WOS研究方向Crystallography ; Physics
WOS类目Crystallography ; Physics, Condensed Matter
WOS记录号WOS:000387145700003
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6366
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
盐湖资源综合利用工程技术中心
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Salt Lake Comprehens Utilizat Resources Engn Tech, Xining, Peoples R China
2.Univ Chinese Acad Sci, Beijing, Peoples R China
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GB/T 7714
Lin, Feng,Dong, Yaping,Peng, Jiaoyu,et al. A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property[J]. PHASE TRANSITIONS,2016,89(10):996-1005.
APA Lin, Feng,Dong, Yaping,Peng, Jiaoyu,Wang, Liping,Li, Wu,&Yang, Bo.(2016).A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property.PHASE TRANSITIONS,89(10),996-1005.
MLA Lin, Feng,et al."A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property".PHASE TRANSITIONS 89.10(2016):996-1005.
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