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A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property
Lin, Feng1,2; Dong, Yaping1; Peng, Jiaoyu1; Wang, Liping1,2; Li, Wu1; Yang, Bo1
2016-10-01
发表期刊PHASE TRANSITIONS
卷号89期号:10页码:996-1005
关键词Slow Evaporation Method Nonlinear Optical Hydrate Borate
摘要A new acentric mixed metal borate of composition K2Ba[B4O5(OH)(4)](2)10H(2)O, has been successfully obtained by slow evaporation solution method. The compound crystallizes in the Orthorhombic space group Pna21 (No.33) with a = 16.8668(7) angstrom, b = 13.0903(5) angstrom, c = 11.5529(5) angstrom and Z = 4. [B4O5(OH)(4)](2-) clusters serve as fundamental building unit linking with BaO8, K1O(6), K2O(7) by common O atoms to form three-dimensional layer structure. The second harmonic generation measurements in the powder samples reveal that the compound exhibits approximately 0.5times that of KH2PO4 (KDP) and phase matching.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6366
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
盐湖资源综合利用工程技术中心
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Salt Lake Comprehens Utilizat Resources Engn Tech, Xining, Peoples R China
2.Univ Chinese Acad Sci, Beijing, Peoples R China
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GB/T 7714
Lin, Feng,Dong, Yaping,Peng, Jiaoyu,et al. A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property[J]. PHASE TRANSITIONS,2016,89(10):996-1005.
APA Lin, Feng,Dong, Yaping,Peng, Jiaoyu,Wang, Liping,Li, Wu,&Yang, Bo.(2016).A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property.PHASE TRANSITIONS,89(10),996-1005.
MLA Lin, Feng,et al."A new acentric borate of K2Ba[B4O5(OH)(4)](2)center dot 10H(2)O: synthesis, structure and nonlinear optical property".PHASE TRANSITIONS 89.10(2016):996-1005.
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