SYNTHESIS AND EFFICIENCY OF A CHELATING FIBER FOR PRECONCENTRATING OF TRACE ELEMENTS

ISL OpenIR > 青海盐湖研究所知识仓储

	SYNTHESIS AND EFFICIENCY OF A CHELATING FIBER FOR PRECONCENTRATING OF TRACE ELEMENTS
	Bao, Amin; Zheng, Hong; Liu, Zeyu; Huang, Dongfang; Li, Bo; Wang, Shuya; Wang, Bin; Yang, Jinsheng; Fan, Chengliang
第一作者	Bao, Amin
	2017
发表期刊	FRESENIUS ENVIRONMENTAL BULLETIN
ISSN	1018-4619
卷号	26 期号:11 页码:6364-6372
关键词	Chelating Fiber Metal Ions Preconcentration Separation Icp-oes
摘要	A new poly(acryl-p-toluenesulfonamideamidine-p-toluenesulfonylamide) chelating fiber containing S, N and O elements was synthesized simply and rapidly from polyacrylonitrile fiber and p-toluenesulfonamide, and used for preconcentration and separation for traces of Sn(IV), V(V), Bi(III) and Mn(II) ions from waste water and mineral sample solution. These ions can be quantitatively been enriched at pH 3.0 at a flow rate of 5 mL min(-1), and desorbed quantitatively with 15 mL of 4 mol L-1 HCl solution from the fiber column, with the recoveries over 95 %. Twenty to hundred-fold excesses of foreign ions cause little interference with the enrichment and determination of analyzed ions. The saturated adsorption capacities of the fiber were in range of 39 - 95 mg g(-1). The relative standard deviations (RSDs) for the enrichment and determination of 10 ng ml(-1) of Mn(II) and V(IV) and 100 ng ml(-1) of Bi(III) and Sn(IV) were in the range 0.56 % - 2.6 %. The results obtained for these ions in real solution samples by this method were basically in agreement with the given values with average errors of less than 5.0 %. The chelating mechanism was primarily discussed by FT-IR spectra. The experiments show that the method is rapid, precise, simple and convenience to use.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/6402
专题	青海盐湖研究所知识仓储盐湖资源综合利用工程技术中心
推荐引用方式 GB/T 7714	Bao, Amin,Zheng, Hong,Liu, Zeyu,et al. SYNTHESIS AND EFFICIENCY OF A CHELATING FIBER FOR PRECONCENTRATING OF TRACE ELEMENTS[J]. FRESENIUS ENVIRONMENTAL BULLETIN,2017,26(11):6364-6372.
APA	Bao, Amin.,Zheng, Hong.,Liu, Zeyu.,Huang, Dongfang.,Li, Bo.,...&Fan, Chengliang.(2017).SYNTHESIS AND EFFICIENCY OF A CHELATING FIBER FOR PRECONCENTRATING OF TRACE ELEMENTS.FRESENIUS ENVIRONMENTAL BULLETIN,26(11),6364-6372.
MLA	Bao, Amin,et al."SYNTHESIS AND EFFICIENCY OF A CHELATING FIBER FOR PRECONCENTRATING OF TRACE ELEMENTS".FRESENIUS ENVIRONMENTAL BULLETIN 26.11(2017):6364-6372.